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Specifications, Properties, Uses, SDS of Calcium Propionate USP NF FCC Food Grade Manufacturer Supplier Exporter Wholesale & Small Packs, CAS Number 4075-81-4.
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Calcium Propionate CAS Number 4075-81-4For Properties Specifications Uses of Calcium Propionate Click Properties, Specifications, Uses, Price, Process of Calcium Propionate Manufacturer.
For For SDS MSDS Sheet of Calcium Propionate Click SDS Safety Data Sheet MSDS Sheet of Calcium Propionate Manufacturer.
The Properties, Specifications, Monograph and Uses of Calcium Propionate:
CAS number 4075-81-4; EINECS EC number 223-795-8, HS Code: 29155000 or 29159090, Molecular formula C6H10CaO4; Molecular Weight 186.22
Calcium propanoate or calcium propionate has the formula Ca(C2H5COO)2. It is the calcium salt of propanoic acid. Calcium propionate is a naturally occurring organic salt formed by a reaction between calcium hydroxide and propionic acid. It is commonly used as a food additive, known by E-number E282. It help preserve various food products, like bread, biscuits, cheeses, powdered milk, whey, yogurt, soft drinks, fruit drinks, beers, malt beverages, wine, cider, hot dogs, ham, lunch meats, etc. Calcium propionate has been approved for use by the Food and Drug Administration (FDA), World Health Organization (WHO). FDA labels it as GRAS, “generally recognized as safe”. Calcium propionate can be used as a fungicide on fruit.
Calcium Propionate USP NF Grade Specifications:
C6H10CaO4 --- 186.22 CAS 4075-81-4DEFINITION
Calcium Propionate contains NLT 98.0% and NMT 100.5% of calcium propionate (C6H10CaO4), calculated on the anhydrous basis.IDENTIFICATION
A. A solution of Calcium Propionate (1 in 20) imparts a transient yellowish red color to a nonluminous flame.ASSAY
Limit of Fluoride: To pass the test. --- NMT 30 µg/g
Procedure
Sample solution: 4 mg/mL of Calcium Propionate
Analysis: While stirring, preferably with a magnetic stirrer, add 30 mL of 0.05 M edetate disodium from a 50-mL burette to 100 mL of the Sample solution. Add 15 mL of 1 N sodium hydroxide and 300 mg of hydroxy naphthol blue indicator and continue the titration to a blue endpoint. Each mL of 0.05 M edetate disodium is equivalent to 9.311 mg of calcium propionate (C6H10CaO4).
Acceptance criteria: 98.0% to 100.5% on the anhydrous basis
Limit of Lead: To pass the test. --- NMT 2 µg/g
Magnesium (as MgO): To pass the test. --- (about 0.4%).
Water-Insoluble Substances:
Sample: 10 g
Analysis: Dissolve the Sample in 100 mL of hot water, pass through a tared filtering crucible, wash the insoluble residue with hot water, and dry at 105C to constant weight.
pH: 7.5 to 10.5, in a solution (1 in 10)
Water Determination: NMT 5.0%
Loss on Drying:
Analysis: Dry at 105C for 2 h.
Acceptance criteria: NMT 4%
Packaging and Storage: Store in tightly closed containers. No storage requirements specified.
Calcium Propionate FCC Food Grade:
(CH3CH2COO)2Ca
C6H10CaO4 Formula weight 186.22
INS: 282 CAS: 4075-81-4DESCRIPTION
Calcium Propionate occurs as white crystals or as a crystalline solid. The pH of a 1:10 aqueous solution is between 7.5 and 10.5. One-gram dissolves in about 3 mL of water.
Function: Preservative; mould inhibitor.REQUIREMENTS
Identification:
A. A 1:20 aqueous solution gives positive tests for Calcium.
B. Upon ignition at a relatively low temperature, a sample yields an alkaline residue that effervesces with acids.
Assay: Not less than 98.0% and not more than 100.5% of C6H10CaO4, calculated on the anhydrous basis.
Fluoride: Not more than 0.003%.
Insoluble Substances: Not more than 0.2%.
Lead: Not more than 2 mg/kg.
Magnesium (as MgO): Passes test (about 0.4%).
Water: Not more than 5.0%.
The MSDS-SDS Hazard Statement of Calcium Propionate:
Calcium propionate or Calcium dipropionate or Propionic acid calcium salt
SDS, Safety Data Sheet
MSDS, Material Safety Data Sheet 31-Jul-211. Product Identification
Product Name & Other Names: Calcium propionate or Propionic acid, calcium salt or Calcium dipropionate.
CAS No.: 4075-81-4
EINECS, EC Number: 223-795-8
Molecular Weight: 186.22
Chemical Formula: (CH3CH2COO)2Ca
Relevant uses and uses advised against (if any): Laboratory and Industrial Manufacturing.
SUPPLIER: As per letterhead.2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
This substance is not classified as dangerous according to Directive 67/548/EEC.Labeling according to GHS & Regulation (EC) No 1272/2008
GHS Label Elements
NONESignal Word: None
Precautionary statements:
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P281: Use personal protective equipment as required.
P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.3. Composition/Information on Ingredients
Product Name & Other Names: Calcium propionate or Propionic acid, calcium salt or Calcium dipropionate.
CAS No.: 4075-81-4
EINECS, EC Number: 223-795-84. First Aid Measures
Always seek medical attention after first aid measures are provided.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.5. Fire Fighting Measures
Flammability of the Product: May be combustible at high temperature.
Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: Fumes, Calcium Oxide Carbon dioxide & Carbon Monoxide.
Explosion: Slightly explosive on heating.
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Use water spray, alcohol-resistant foam, dry chemical, or carbon dioxide.
Extinguishing Media Not recommended: Avoid using solid water jet as it may scatter the fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place. On decomposition it may emit carbon monoxide. Containers may explode on heating.6. Accidental Release Measures
Personal precautions, protective equipment, and emergency procedures: Ventilate area of leak or spill. Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment cleanup procedures and Storage: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g., sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep-up and remove to an approved disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law.7. Handling and Storage
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents.8. Exposure Controls/Personal Protection
Airborne Exposure Limits: Not Specified.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full-face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.9. Physical and Chemical Properties
Appearance: Colorless or white powder or crystals.
Odor: It is odorless.
Odor threshold: Not available.
pH: Not available.
Relative density: around 3.13
Melting Point: 681C 1257F
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: It is soluble in water.
Viscosity: Not available.
Molecular formula: (CH3CH2COO)2Ca
Molecular weight: 186.210. Stability and Reactivity
Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits carbon monoxide & fumes when heated to decomposition. It may form calcium oxide harmful gases.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents.
Conditions to Avoid: Incompatibles and moisture.11. Toxicological Information
Toxicity data
ORL-RAT LD50 3290 mg kg-1
ORL-MAM LD50 2350 mg kg-1
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as probable or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Mutagenic Effects: NA
Teratogenic Effects:
Developmental Toxicity: NA.12. Ecological Information
Environmental Fate: Not classified as environmentally hazardous.
Environmental Toxicity: This chemical is expected to cause little oxygen depletion in aquatic systems.
Persistence and Degradability: Unlikely to persist due to water solubility.
Mobility: Likely to be mobile due to water solubility.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.
Toxicity of the Products of Biodegradation: The products of degradation and the product are not classed as toxic.13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state, and local requirements.
14. Transport Information
Land Transport DOT USA, TDG Canada & ADR/RID Europe: Not dangerous goods.
Sea Transport IMO/IMDG: Not dangerous goods.
Air Transport IATA/ICAO: Not dangerous goods.15. Regulatory Information
SARA 311/312 Hazards: Not Listed.
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.Section 16 - Additional Information
DISCLAIMER: The information and recommendations set forth herein are presented in good faith and believed correct as of the date hereof. It is compiled from various sources, and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules, or insurance requirements applicable. This SDS MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a professionally trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. This shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. In no case shall our company be liable to loss or damages by the product user.
Calcium Propionate Manufacturers, Suppliers, Exporters, Wholesalers:
King of Chemicals manufacturers
Plot No. 2900/46&47 + 2900/163to167, GIDC, Ankleshwar, Dist. Bharuch, India
India, USA, UAE
TEL: (Office) 91-22-23774610, 91-22-23723564e-mail: info@kingofchemicals.com
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