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Specifications, Properties, Uses, SDS of Sodium Metabisulphite or Sodium Metabisulfite USP NF BP Ph Eur IP Reagent FCC Food Grade Manufacturer Supplier Exporter Wholesale & Small Packs, CAS Number 7681-57-4.

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Sodium Metabisulphite or Sodium Metabisulfite CAS Number 7681-57-4

For Properties Specifications Uses of Sodium Metabisulphite or Sodium Metabisulfite Click Properties, Specifications, Uses, Price, Process of Sodium Metabisulphite or Sodium Metabisulfite Manufacturer.

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The Properties, Specifications, Monograph and Uses of Sodium Metabisulphite or Sodium Metabisulfite:

CAS Number: 7681-57-4, Molecular Weight: 190.11, Chemical Formula: Na2S2O5, EINECS EC Number: 231-673-0 HS Code 28321090 or 28321010

Sodium metabisulfite or sodium pyrosulfite or Sodium metabisulphite or Sodium pyrosulphite is an inorganic compound of chemical formula Na2S2O5. The substance is sometimes referred to as disodium metabisulfite. It is used as a disinfectant, antioxidant, and preservative agent. Sodium metabisulfite is added as an excipient to medications. it is used as a rust-stain remover and in in photography.

Sodium Metabisulfite USP NF Grade Specifications:
Na2S2O5 --- 190.11
Disulfurous acid, disodium salt;
Disodium pyrosulfite CAS 7681-57-4

DEFINITION
Sodium Metabisulfite ;contains an amount of sodium metabisulfite (Na2S2O5) equivalent to NLT 65.0% and NMT 67.4% of SO2.

IDENTIFICATION
A. Identification Tests-General, Sodium and Sulfite: A solution (1 in 20) meets the requirements.

ASSAY
Procedure
Sample: 200 mg of Sodium Metabisulfite
Blank: 50.0 mL of 0.1 N iodine, accurately measured
Titrimetric system
Mode: Residual titration
Titrant: 0.1 N iodine
Back-titrant: 0.1 N sodium thiosulfate
Endpoint detection: Visual
Analysis: Add the Sample to 50.0 mL of 0.1 N iodine in a glass-stoppered conical flask, and swirl to dissolve. Allow to stand for 5 min, protected from light. Add 1 mL of hydrochloric acid, and titrate the excess iodine with Back-titrant, adding 3 mL of starch as the endpoint is approached. Perform a blank determination.
Calculate the percentage of sodium metabisulfite (Na2S2O5) in the portion of Sodium Metabisulfite taken:
Result = {[(V B − V S) × N& × F]/W} × 100
V B = Back-titrant volume consumed by the Blank (mL)
V S = Back-titrant volume consumed by the Sample (mL)
N = Back-titrant normality (mEq/mL)
F = equivalency factor, 32.03 mg/mEq
W = Sample weight (mg)
Acceptance criteria: 65.0% to 67.4% of SO2

Limit of Chloride: To pass the test. --- 0.05%
Limit of Thiosulfate: To pass the test. --- 0.05%
Iron: To pass the test. --- NMT 20 ppm
Packaging and Storage: Preserve in well-filled, tight containers, and avoid exposure to excessive heat.

Specifications of Sodium Metabisulphite BP Ph Eur Grade
Sodium Pyrosulphite
Na2S2O5

DEFINITION
Sodium metabisulphite also called sodium disulphite.
Content: 95.0 per cent to 100.5 per cent.

CHARACTERS
Appearance: White or almost white, crystalline powder or colourless crystals.
Solubility: Freely soluble in water, slightly soluble in ethanol (96 per cent).

IDENTIFICATION
A. pH 3.5 to 5.0 for solution S.
B. To 0.4 ml of iodinated potassium iodide solution R add 8 ml of distilled water R and 1 ml of solution S diluted 1 to 10 in distilled water R. The solution is colourless and gives reaction of sulphate.
C. Solution S gives reaction of sodium.

TESTS
Solution S: Dissolve 5.0 g in carbon dioxide-free water prepared from distilled water and dilute to 100 ml with the same solvent.
Appearance of solution: Solution S is clear and colourless.
pH: 3.5 to 5.0 for solution S.
Thiosulphate: To 5 ml of solution S add 5 ml of dilute hydrochloric acid R. The solution remains clear for at least 15 min.
Arsenic: Maximum 5 ppm.
Iron: Maximum 20 ppm, determined on solution S.
Heavy metals: Maximum 20 ppm.


Specifications of Sodium Metabisulfite FCC Food Grade
Sodium Pyrosulfite
Na2S2O5 Formula wt 190.11
INS: 223 CAS: 7681-57-4

DESCRIPTION
Sodium Metabisulfite occurs as colorless crystals or as a white to yellow, crystalline powder. It is freely soluble in water and slightly soluble in alcohol. Its solutions are acid to litmus.
Function: Preservative; antioxidant.

REQUIREMENTS
Identification: A 1:10 aqueous solution gives positive tests for Sodium and for Sulfite.
Assay
: Not less than 90.0% and not more than 100.5% of Na2S2O5.
Iron: Not more than 10 mg/kg.
Lead: Not more than 2 mg/kg.
Selenium: Not more than 5 mg/kg.


Sodium Metabisulfite Analytical Reagent
Disodium Disulfite
Na2S2O5
Formula Wt 190.11
CAS Number 7681-57-4

REQUIREMENTS
Assay: min 97.0% Na2S2O5

MAXIMUM ALLOWABLE
Insoluble matter: 0.005%
Chloride (Cl): 0.05%
Thiosulfate (S2O3): 0.05%
Heavy metals (as Pb): 0.001%
Iron (Fe): 0.002%


The MSDS-SDS Hazard Statement of Sodium Metabisulphite or Sodium Metabisulfite:

Sodium Metabisulfite or Sodium Metabisulphite SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet
25-Jul-21

1. Product Identification

Product Name & Other Names: Sodium Metabisulfite or Sodium Metabisulphite or Disulfurous acid, Disodium salt or Fertisilo or Pyrosulfurous acid, disodium salt or Sodium disulfite or Disodium pyrosulfite or Sodium pyrosulfite.
CAS No.: 7681-57-4 Sodium Metabisulfite or Sodium Metabisulphite.
EINECS EC Number: 231-673-0
Molecular Weight: 190.11
Chemical Formula: Na2S2O5 (sodium metabisulfite)
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Details of the supplier of the safety data sheet: As per letter head.

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, oral Category 4, H302
Acute toxicity, dermal Category 5, H315
Serious eye damage/eye irritation Category 1, H318

Labeling according to GHS USA & Regulation (EC) No 1272/2008

GHS Label Elements
Corrosive
Corrosive

Signal Words: Danger

Hazard statements:
H302: Harmful if swallowed.
H315: Causes skin irritation.
H318: Causes serious eye damage.
EUH031: Contact with acids liberates toxic gas.

Precautionary statements:
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 Wash with plenty of water and soap thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P281: Wear protective equipment for hands, eyes, face and respiratory tract.
P270: Do not eat, drink or smoke when using this product.
P301 + P330: IF SWALLOWED: rinse mouth.
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P332+P313 : If skin irritation occurs: Get medical advice/attention.
P312 : Call a POISON CENTER or doctor/physician if you feel unwell.
P362: Take off contaminated clothing and wash before reuse.
P501: Dispose of contents/container to hazardous or special waste collection point.

3. Composition/Information on Ingredients

Product Name & Other Names: Sodium Metabisulfite or Sodium Metabisulphite or Disulfurous acid, Disodium salt or Fertisilo or Pyrosulfurous acid, disodium salt or Sodium disulfite or Disodium pyrosulfite or Sodium pyrosulfite.
CAS No.: 7681-57-4
EINECS EC Number: 231-673-0

4. First Aid Measures

Always seek medical attention after first aid measures are provided.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

5. Fire Fighting Measures

Fire: Not considered to be a fire hazard.
Explosion: Not considered to be an explosion hazard.
Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Do not allow water runoff to enter sewers or waterways.
Extinguishing Media Not recommended: None specified.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

6. Accidental Release Measures

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment cleanup procedures and Storage: Do not inhale dust, vapors, mist, or gas. Avoid dust formation. Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g., sand, earth, diatomaceous earth, vermiculite). Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law.

7. Handling and Storage

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, acids, alkalis, sodium nitrite, aluminum powder. Avoid moisture, water, ice.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: ACGIH Threshold Limit Value (TLV) 5mg/m3 (TWA)
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): If the exposure limit is exceeded, a half-face respirator with an acid gas cartridge may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. A full-face piece respirator with an acid gas cartridge may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full-face piece positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron, or coveralls, as appropriate, to prevent skin contact. (Neoprene, polyvinyl chloride).
Eye Protection: Use chemical safety goggles and/or full-face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. Physical and Chemical Properties

Appearance: White to yellow white crystalline granules.
Odor: Slight odor of sulfur dioxide.
Odor threshold: Not available.
pH: Aqueous solution is acidic.
Relative density: around 1.48
Melting Point: 150C (302F).
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Very soluble in water, insoluble in alcohol.
Viscosity: Not available.
Molecular Weight: 190.11
Chemical Formula: Na2S2O5 (sodium metabisulfite)

10. Stability and Reactivity

Stability: Product is normally stable. Air and moisture sensitive and releases sulfur dioxide slowly at ambient temperatures. Sodium Metabisulfite will decompose on heating to form sodium sulfate. Contact with moisture (water, wet ice, etc.), will release toxic sulfur dioxide gas.
Hazardous Decomposition Products: Oxides of sulfur and sodium may form when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Water, acids, alkalis, sodium nitrite, oxidizers, aluminum powder.
Conditions to Avoid: Moisture, heat, flames, ignition sources and incompatibles.

11. Toxicological Information

LD50 Oral - Rat - 1.540 mg/kg
LD50 Dermal - Rat - > 2.000 mg/kg
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as possible or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Teratogenic Effects: Not available.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.

12. Ecological Information

Toxicity to fish: LC50 - Oncorhynchus mykiss (rainbow trout) - 150 - 220 mg/l - 96 h
Toxicity to daphnia and other aquatic invertebrates: EC50 - Daphnia magna (Water flea) - 89 mg/l - 24 h
Toxicity to algae: IC50 - Desmodesmus subspicatus (green algae) - 48 mg/l - 72 h
Toxicity to bacteria: Pseudomonas putida - 56 mg/l - 17 h
Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Dispose of container of Sodium Metabisulfite and unused contents in accordance with legal requirements.

14. Transport Information

Land Transport DOT USA, TDG Canada & ADR/RID Europe: Not regulated.
Sea Transport IMDG/IMO: Not regulated.
Air Transport IATA/ICAO: Not regulated.

15. Regulatory Information

USA:
California Proposition 65
: Not listed.
SARA 311/312: Acute health hazard. See section 2.

Section 16 - Additional Information

DISCLAIMER: The information and recommendations set forth herein are presented in good faith and believed correct as of the date hereof. It is compiled from various sources, and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules, or insurance requirements applicable. This SDS MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a professionally trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. This shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. In no case shall our company be liable to loss or damages by the product user.

Muby Chem P Ltd

Sodium Metabisulphite or Sodium Metabisulfite Manufacturers, Suppliers, Exporters, Wholesalers:

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Plot No. 2900/46&47 + 2900/163to167, GIDC, Ankleshwar, Dist. Bharuch, India
India, USA, UAE
TEL: (Office) 91-22-23774610, 91-22-23723564

e-mail: info@kingofchemicals.com

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