Specifications, Uses, SDS of Methyl Salicylate Manufacturers

	King of Chemicals
Specifications, Properties, Uses, SDS of Methyl Salicylate or Wintergreen Oil BP Ph Eur IP FCC Food Grade Manufacturer Supplier Exporter Wholesale & Small Packs, CAS Number 119-36-8.
King of Chemicals has several associated companies having accreditations like cGMP, GLP - FDA Approved Good Manufacturing Practice and Good Laboratory Practice of WHO standard, ISO-9001, ISO-14001, ISO/IEC 17025, ISO ISO-45000, HACCP, FSSC 220000, FSSAI, "REACH" Registered, Kosher & Halal Certified. DMF support can be made available if needed. We offer USP NF BP Ph Eur EP IP JP Analytical Reagent FCC Food Grade Chemicals & Nutraceuticals.

Muby Chem Pvt. Ltd. is a several decades old group of companies, engaged in manufacturing, supplying, distributing, wholesale supplies of Methyl Salicylate or Wintergreen Oil for actual users, including retail or small pack supplies for research and development work.

We supply fine and speciality chemicals, pharmaceutical excipients, mineral fortifiers in chemically pure, analytical reagent grade, IP BP USP Ph Eur EP JP and other pharmaceutical grade monograph including FCC Food grade chemicals and Nutraceuticals at best prices. We and/or our associated units have all the facilities to supply as per cGMP standard observing good manufacturing practice and good laboratory practice. We can assure low microbial count and also offer a test certificate for the same. We maintain warehouses across USA, India, and UAE. Our group exports to USA, Canada, Mexico, Argentina, Brazil, Chile, Korea, Malaysia, Thailand, Indonesia, Europe, and several other parts of the world. We supply in wholesale container loads to small pack of few grams. Solid products may be specified for it size and shape as desired by the buyer.

The Properties, Specifications, Monograph and Uses of Methyl Salicylate or Wintergreen Oil:

CAS Number: 119-36-8, EINECS EC Number: 204-317-7, FEMA Number: 2745, Molecular Formula: C8H8O3, Molecular Weight: 152.15, HS Code 29182990 or 29182310

Methyl salicylate (oil of wintergreen or wintergreen oil) is an organic compound with the formula C6H4(OH)(CO2CH3). It is the methyl ester of salicylic acid. It is a colorless, viscous liquid with a sweet, fruity odor reminiscent of root beer. It is also used as a fragrance and as a flavoring agent. Methyl salicylate is used in high concentrations as a rubefacient and analgesic in deep heating liniments to treat joint and muscular pain. It is used as a flavoring agent in chewing gum and mints. it is also used as a penetrating oil to loosen rusted parts. Methyl salicylate is an external analgesic available in over-the-counter (OTC) medicines that temporarily relieve minor body aches and muscle and joint pain associated with backache, arthritis, strains, sprains, and bruises.

Methyl Salicylate BP Ph Eur Grade Specifications:
C8H8O3 --- 152.1 --- CAS 119-36-8
Action and use: Counter-irritant.

DEFINITION
Methyl 2-hydroxybenzoate.
Content: 99.0 per cent m/m to 100.5 per cent m/m.

CHARACTERS
Appearance: Colourless or slightly yellow liquid.
Solubility: Very slightly soluble in water, miscible with ethanol (96 per cent) and with fatty and essential oils.

IDENTIFICATION
A. Heat 0.25 mL with 2 mL of dilute sodium hydroxide solution on a water-bath for 5 min. Add 3 mL of dilute sulfuric acid. A crystalline precipitate is formed. Filter. The precipitate washed with water R and dried at 100C to 105C, melts at 156C to 161C.
B. To 10 mL of a saturated solution add 0.05 mL of ferric chloride solution R1. A violet colour develops.

TESTS
Appearance of solution: The solution is clear and not more intensely coloured than reference solution.
To 2 mL add 10 mL of ethanol (96 per cent) R.
Acidity: Dissolve 5.0 g in a mixture of 0.2 mL of bromocresol green solution and 50 mL of ethanol (96 per cent) previously neutralised to a blue colour by addition of 0.1 M sodium hydroxide. Not more than 0.4 mL of 0.1 M sodium hydroxide is required to restore the blue colour.
Relative density: 1.180 to 1.186.
Refractive index: 1.535 to 1.538.

ASSAY
Dissolve 0.500 g in 25 mL of ethanol (96 per cent). Add 0.05 mL of phenol red solution and neutralize with 0.1 M sodium hydroxide. To the neutralized solution add 50.0 mL of 0.1 M sodium hydroxide and heat under a reflux condenser on a water-bath for 30 min. Cool and titrate with 0.1 M hydrochloric acid. Calculate the volume of 0.1 M sodium hydroxide used in the saponification. Carry out a blank titration.
1 mL of 0.1 M sodium hydroxide is equivalent to 15.21 mg of C8H8O3.

Wintergreen Oil FCC Food and Flavoring Grade
Gaultheria Oil
CAS: [68917-75-9]

DESCRIPTION
Wintergreen Oil occurs as a colorless to yellow liquid withthe characteristic odor and taste of wintergreen. It is obtained by maceration and subsequent distillation with steam from the leaves of Gualtheria procumbens L. (Fam. Ericaceae) or from the bark of Betula lenta L. (Fam. Betulaceae). It boils, with decomposition, between 219C and 224C. It is soluble in alcohol and in glacial acetic acid, and it is very slightly soluble in water.
Function: Flavoring agent.

REQUIREMENTS
Identification:-
A. Shake 1 drop of sample with about 5 mL of water, and add 1 drop of ferric chloride. A deep violet color appears.
B. The infrared absorption spectrum of the sample exhibits relative maxima at the same wavelengths as those of a typical spectrum as shown in the section on Infrared Spectra, using the same test conditions as specified therein.
Assay: Not less than 98.0% and not more than 100.5% of methyl salicylate (C8H8O3).
Acid Value: Not more than 1.0.
Angular Rotation: Slightly levorotatory, exhibiting a rotation of not more than −1.5°.
Refractive Index: Between 1.535 and 1.538 at 20C.
Solubility in Alcohol: Passes test.
Specific Gravity: Between 1.176 and 1.182.

Methyl Salicylate SDS, Safety Data Sheet
MSDS, Material Safety Data Sheet 08-Aug-21

Product Name & Other Names: Methyl Salicylate or 2-Hydroxybenzoic acid Methyl ester or Methyl 2-hydroxybenzoate or Oil of wintergreen or Methoxybenzoic Acid.
CAS No.: 119-36-8
EINECS EC Number: 204-317-7
Molecular Weight: 152.15
Chemical Formula: 2-(HO)C6H4CO2CH3
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Acute toxicity, oral Category 4, H302
Serious eye damage/eye irritation Category 2A, H319

Hazard statements:
H302: Harmful if swallowed.
H319: Causes serious eye irritation.

Precautionary statements:
P264: Wash … thoroughly after handling.
P270: Do not eat, drink, or smoke when using this product.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P330: Rinse mouth.
P301+312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.
P501: Dispose of contents/container in accordance with local/regional/national/international regulation.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

Flammability of the Product: Combustible at high temperature. Vapors can travel to a source of ignition and flash back.
Auto-Ignition Temperature: 454C.
Flash Points: 96C Closed Cup.
Flammable Limits: Not available.
Products of Combustion: Fumes, Carbon dioxide & Carbon Monoxide.
Fire: Methyl Salicylate is flammable on heating.
Explosion: Explosive on heating.
Fire Extinguishing Media: Use means suitable for extinguishing surrounding fire. Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Extinguishing Media Not recommended: Avoid using solid water jet as it may scatter the fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place. On decomposition it may emit carbon monoxide. Containers may explode on heating.

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment cleanup procedures and Storage: Avoid touching the spilled material. Do not let the product enter drains. Avoid breathing vapors, mist, or gas. Ensure adequate ventilation. Contain spilled material. Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow evacuating as per law.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, acids, and bases. Keep away from heat, sun light.

Airborne Exposure Limits: Not Specified.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full-face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: Colorless to yellowish red liquid.
Odor: Strong typical wintergreen.
Odor threshold: Not available.
pH: Not available.
Relative density: Not available.
Boiling Point: 223C.
Melting Point: -8.6C.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: It is slightly soluble in water.
Viscosity: Not available.
Molecular Weight: 152.15
Molecular Formula: 2-(HO)C6H4CO2CH3

Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits carbon monoxide & fumes when heated to decomposition. It may form harmful gases.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents, acids, strong bases.
Conditions to Avoid: Incompatible materials, light, dust generation, excess heat, exposure to moist air or water.

Toxicity data
ORAL-RAT LD50 887 mg kg-1
ORAL-Mouse LD50 1110 mg kg-1
Dermal-Rabbit LD50 > 5.000 mg/kg.
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as possible or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Teratogenic Effects: Not available.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.

Toxicity to fish: static test LC50 - Danio rerio (zebra fish) - > 100 mg/l - 96 h
Toxicity to algae: static test EC50 - Desmodesmus subspicatus (green algae) - 27 mg/l - 72 h
Environmental Fate: This substance is expected to have a high biological oxygen demand. It is readily biodegradable and has low bioconcentration potential.
BOD5 and COD: This substance is expected to have a high biological oxygen demand.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with law.

Land transport DOT USA, TDG Canada & ADR/RID Europe: Not regulated.
Sea Transport IMDG/IMO: Not regulated.
Air transport ICAO/IATA: Not regulated.

USA:
SARA 311/312 Hazards: Acute Health Hazard. See section 2.
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

Methyl Salicylate or Wintergreen Oil Manufacturers, Suppliers, Exporters, Wholesalers:

Plot No. 2900/46&47 + 2900/163to167, GIDC, Ankleshwar, Dist. Bharuch, India
India, USA, UAE
TEL: (Office) 91-22-23774610, 91-22-23723564

If I give you “My Word” Nobody can undo it.
If I sign an “Agreement” my Lawyer will undo it

Our products are for industrial and laboratory use only. The user must test the material before use. We are not dispensing chemists or druggist and do not offer over the counter type (OTC) products for medical use by individuals.

Specifications, Properties, Uses, SDS of Methyl Salicylate or Wintergreen Oil BP Ph Eur IP FCC Food Grade Manufacturer Supplier Exporter Wholesale & Small Packs, CAS Number 119-36-8.

Methyl Salicylate or Wintergreen Oil Manufacturers, Suppliers, Exporters, Wholesalers: