Specifications, Uses, SDS of Benzoic Acid Manufacturers

	King of Chemicals Manufacturers
Specifications, Properties, Uses, SDS of Benzoic Acid USP BP Ph Eur Reagent FCC Food Grade Manufacturer Supplier Exporter Wholesale & Small Packs, CAS Number 65-85-0.
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CAS Number 65-85-0, EINECS EC Number 200-618-2, HS code 29163110, Molecular Weight 122.1, Chemical Formula C7H6O2

Benzoic acid is a white or colorless solid with the formula C6H5CO2H. It is the simplest aromatic carboxylic acid. Benzoic acid mainly consumed in the production of phenol. Benzoic acid has E number of E210 and itself and its salts are used as a food preservative.

Specifications of Benzoic Acid USP
C7H6O2 --- 122.12
Benzoic acid CAS 65-85-0.

Benzoic Acid contains not less than 99.5 percent and not more than 100.5 percent of C7H6O2, calculated on the anhydrous basis.

Identification: Prepare a saturated solution of Benzoic Acid in water, and filter twice. To one portion of the filtrate add ferric chloride TS: a salmon-colored precipitate is formed. To a separate 10-mL portion of the filtrate add 1 mL of 7 N sulfuric acid and cool the mixture: a white precipitate forms in about 10 minutes; this precipitate is soluble in ether.
Congealing range: between 121 and 123.
Water: not more than 0.7%, a 1 in 2 solution of methanol in pyridine being used as the solvent.
Readily carbonizable substances: Dissolve 500 mg in 5 mL of sulfuric acid: the solution has no more color than Matching Fluid Q.
Residue on ignition: not more than 0.05%.
Heavy metals: Dissolve 2.0 g in 25 mL of acetone, and add 2 mL of water. Add 1.2 mL of thioacetamide-glycerin base TS and 2 mL of pH 3.5 Acetate Buffer, and allow to stand for 5 minutes: any color produced is not darker than that of a control made with 25 mL of acetone, 2.0 mL of Standard Lead Solution, and treated in the same manner. The limit is 10µg per g.
Readily oxidizable substances: Add 1.5 mL of sulfuric acid to 100 mL of water, heat to boiling, and add 0.1 N potassium permanganate, drop wise, until the pink color persists for 30 seconds. Dissolve 1.00 g of Benzoic Acid in the hot solution, and titrate with 0.1 N potassium permanganate VS to a pink color that persists for 15 seconds: not more than 0.50 mL of 0.10 N potassium permanganate is consumed.

Specifications of Benzoic Acid FCC Food Grade
C7H6O2 Formula weight --- 122.12
INS: 210 CAS: 65-85-0

DESCRIPTION
Benzoic Acid occurs as white crystals, scales, or needles. It begins to sublime at about 100C and is volatile with steam. One gram is soluble in 275 mL of water at 25C, in 20 mL of boiling water, in 3 mL of alcohol, in 5 mL of chloroform, and in 3 mL of ether. It is soluble in fixed and in volatile oils and is sparingly soluble in hexane.

REQUIREMENTS
Identification: Dissolve 1 g of sample in a 20:1 (v/v) mixture of water and 1 N sodium hydroxide, filter the solution, and add about 1 mL of ferric chloride TS. A buff-colored precipitate forms.
Assay: Not less than 99.5% and not more than 100.5% of C7H6O2, calculated on the anhydrous basis.
Lead: Not more than 2.0 mg/kg.
Readily Carbonizable Substances: Passes test.
Readily Oxidizable Substances: Passes test.
Residue on Ignition: Not more than 0.05%.
Solidification Point: Between 121-123C.
Water: Not more than 0.7%.

Specifications of Benzoic Acid BP Ph Eur Grade
C7H6O2 -- 122.1 -- CAS 65-85-0

DEFINITION
Benzoic acid contains not less than 99.0 per cent and not more than the equivalent of 100.5 per cent of benzene carboxylic acid.

CHARACTERS
A white, crystalline powder or colourless crystals, odourless or with a very slight characteristic odour, slightly soluble in water, soluble in boiling water, freely soluble in alcohol and in fatty oils.

IDENTIFICATION
A. Melting point 121C to 124C.
B. Solution S (see Tests) gives reaction (a) of benzoates.

TESTS
Solution S: Dissolve 5.0 g in alcohol and dilute to 100 ml with the same solvent.
Appearance of solution: Solution S is clear and colourless.
Carbonizable substances: Dissolve 0.5 g with shaking in 5 ml of sulphuric acid. After 5 min, the solution is not more intensely coloured than reference solution.
Oxidizable substances: Dissolve 0.2 g in 10 ml of boiling water. Cool, shake and filter. To the filtrate add 1 ml of dilute sulphuric acid and 0.2 ml of 0.02 M potassium permanganate. After 5 min, the solution is still coloured pink.
Halogenated compounds and halides: All glassware used must be chloride-free and may be prepared by soaking overnight in a 500 g/l solution of nitric acid, rinsed with water and stored full of water. It is recommended that glassware be reserved for this test.
Solution (a) Dissolve 6.7 g of the substance to be examined in a mixture of 40 ml of 1 M sodium hydroxide and 50 ml of alcohol and dilute to 100.0 ml with water. To 10.0 ml of this solution add 7.5 ml of dilute sodium hydroxide solution and 0.125 g of nickel-aluminium alloy and heat on a water-bath for 10 min. Allow to cool to room temperature, filter into a 25 ml volumetric flask and wash with three quantities, each of 2 ml, of alcohol. Dilute the filtrate and washings to 25.0 ml with water. This solution is used to prepare solution A.
Solution (b) In the same manner, prepare a similar solution without the substance to be examined. This solution is used to prepare solution B.
In four 25 ml volumetric flasks, place separately 10 ml of solution (a), 10 ml of solution (b), 10 ml of chloride standard solution (8 ppm Cl) (used to prepare solution C) and 10 ml of water. To each flask add 5 ml of ferric ammonium sulphate solution, mix and add drop wise and with swirling 2 ml of nitric acid and 5 ml of mercuric thiocyanate solution. Shake. Dilute the contents of each flask to 25.0 ml with water and allow the solutions to stand in a water-bath at 20C for 15 min. Measure at 460 nm the absorbance of solution A using solution B as the compensation liquid, and the absorbance of solution C using the solution obtained with 10 ml of water as the compensation liquid. The absorbance of solution A is not greater than that of solution C (300 ppm).
Heavy metals: 12 ml of solution S complies with limit test B for heavy metals (10 ppm).
Sulphated ash: Not more than 0.1 per cent, determined on 1.0 g.

Specifications of Benzoic Acid Analytical Reagent
C6H5COOH
Formula Wt 122.12
CAS Number 65-85-0

MAXIMUM ALLOWABLE
Residue after ignition: 0.005%
Insoluble in methanol: 0.005%
Chlorine compounds (as Cl): 0.005%
Sulfur compounds (as S): 0.002%
Heavy metals (as Pb): 5 ppm
Substances reducing permanganate: Passes test.

Product Name & Other Names: Benzoic Acid or Benzenecarboxylic acid or benzeneformic acid or phenyl carboxylic acid or phenyl formic acid or dracylic acid.
CAS No.: 65-85-0
EINECS EC Number: 200-618-2
Molecular Weight: 122.12
Chemical Formula: C6H5COOH
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Skin corrosion/irritation (Category 2) H315
Eye damage (Category 1), H318
Specific target organ toxicity, repeated exposure (Category 1) H372

Hazard statements:
H315: Causes skin irritation.
H318: Causes serious eye damage.
H372: Causes damage to organs (Lungs) through prolonged or repeated exposure if inhaled.

Precautionary statements:
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink, or smoke when using this product.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P314 Get Medical advice/attention if you feel unwell.
P302+352: IF ON SKIN: Wash with soap and water.
P332+313: If skin irritation occurs: Get medical advice/attention.
P305+ P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P360 Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.

Product Name & Other Names: Benzoic Acid or Benzenecarboxylic acid or benzeneformic acid or phenyl carboxylic acid or phenyl formic acid or dracylic acid.
CAS No.: 65-85-0
EINECS EC Number: 200-618-2

Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Give several glasses of water to drink to dilute. If large amounts were swallowed, get medical advice.
Skin Contact: Wash exposed area with soap and water. Get medical advice if irritation develops.
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention.

Fire: Flash point: 121C (250F) CC
Auto ignition temperature: 570C (1058F)
Explosion: Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard. Minimum exposable concentration 0.011 g/l. Vapor may explode if ignited in an enclosed area. Vapor from molten benzoic acid may form explosive mixture with air.
Fire Extinguishing Media: Water spray, dry chemical, alcohol foam, or carbon dioxide.
Extinguishing Media Not recommended: Avoid using solid water jet as it may scatter the fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

Personal precautions, protective equipment, and emergency procedures: Ventilate area of leak or spill. Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment cleanup procedures and Storage: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g., sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep-up and remove to an approved disposal container. Neutralize the residue with a dilute solution of sodium carbonate. Finish cleaning by spreading water on the contaminated surface and allow to drain as per law.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents and metals. Keep in a well closed container stored under cold to warm conditions, 2 to 40C, (36 to 104F). Isolate from any source of heat or ignition. Isolate from oxidizing materials. Isolate from flammable materials.

Airborne Exposure Limits: None established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g., lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full-face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: White, needle-like crystals.
Odor: Faint pleasant odor.
Odor threshold: Not available.
pH: 2.8 (saturated solution @ 25 0C)
Relative density: around 1.32
Boiling Point: 249C (480F)
Melting Point: 122C (252F)
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor Density (Air=1): 4.2
Vapor Pressure (mm Hg): 1 @ 96C (205F)
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: 0.29 g / 100 ml. water; sinks in water.
Viscosity: Not available.
Molecular Weight: 122.12
Chemical Formula: C6H5COOH

Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Emits toxic vapors and gas including phenol, benzene, and carbon monoxide when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Oxidizing agents, bases, and metals. Water solutions can react with metals to produce hydrogen gas.
Conditions to Avoid: Heat, flame, ignition sources, dusting, and incompatibles.

Oral rat LD50: 1700 mg/kg; LC50 rat > 26,000mg/L/Hr.; irritation skin rabbit: 500 mg/24H mild; eye rabbit: 100 mg severe; investigated as a mutagen.
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible, or confirmed human carcinogen by IARC.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.

Environmental Fate: When released into the soil or water, Benzoic Acid may leach into groundwater, and it is expected to readily biodegrade.
Environmental Toxicity: No information found.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused Benzoic Acid in accordance with legal requirements.

DOT USA, TDG Canada & ADR/RID Europe: Not dangerous goods.
IMDG/IMO: Not dangerous goods.
IATA/ICAO: Not dangerous goods.

Benzoic Acid Manufacturers, Suppliers, Exporters, Wholesellers:

Plot No. 2900/46&47 + 2900/163to167, GIDC, Ankleshwar, Dist. Bharuch, India
India, USA, UAE
TEL: (Office) 91-22-23774610, 91-22-23723564

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Our products are for industrial and laboratory use only. The user must test the material before use. We are not dispensing chemists or druggist and do not offer over the counter type (OTC) products for medical use by individuals.

Specifications, Properties, Uses, SDS of Benzoic Acid USP BP Ph Eur Reagent FCC Food Grade Manufacturer Supplier Exporter Wholesale & Small Packs, CAS Number 65-85-0.

Benzoic Acid Manufacturers, Suppliers, Exporters, Wholesellers: