Specifications, Uses, SDS of Hydrous Benzoyl Peroxide Manufacturers

	King of Chemicals Manufacturers
Specifications, Properties, Uses, SDS of Hydrous Benzoyl Peroxide USP BP Ph Eur Grade Manufacturer Supplier Exporter Wholesale & Small Packs, CAS Number 94-36-0.
King of Chemicals has several associated companies having accreditations like cGMP, GLP - FDA Approved Good Manufacturing Practice and Good Laboratory Practice of WHO standard, ISO-9001, ISO-14001, ISO/IEC 17025, ISO ISO-45000, HACCP, FSSC 220000, FSSAI, "REACH" Registered, Kosher & Halal Certified. e-CTD and DMF support can be made available if needed. We offer USP NF BP Ph Eur EP IP JP Analytical Reagent FCC Food Grade Chemicals & Nutraceuticals.

Muby Chem Pvt. Ltd. is a several decades old group of companies, engaged in manufacturing, supplying, distributing, wholesale supplies of Hydrous Benzoyl Peroxide for actual users, including retail or small pack supplies for research and development work.

We supply fine and speciality chemicals, pharmaceutical excipients, mineral fortifiers in chemically pure, analytical reagent grade, IP BP USP Ph Eur EP JP and other pharmaceutical grade monograph including FCC Food grade chemicals and Nutraceuticals at best prices. We and/or our associated units have all the facilities to supply as per cGMP standard observing good manufacturing practice and good laboratory practice. We can assure low microbial count and also offer a test certificate for the same. We maintain warehouses across USA, India, and UAE. Our group exports to USA, Canada, Mexico, Argentina, Brazil, Chile, Korea, Malaysia, Thailand, Indonesia, Europe, and several other parts of the world. We supply in wholesale container loads to small pack of few grams. Solid products may be specified for it size and shape as desired by the buyer.

The Properties, Specifications, Monograph and Uses of Hydrous Benzoyl Peroxide:

CAS Number: 94-36-0, EINECS EC Number: 202-327-6, Molecular Formula: (C6H5CO)2O2, Molecular Weight: 242.23, H S Code 29163200.

Hydrous Benzoyl Peroxide appears as odorless white powder or granules. Hydrous Benzoyl Peroxide is used to treat mild to moderate acne. When applied to the skin, benzoyl peroxide works by reducing the acne-causing bacteria and by causing the skin to dry and peel. It has other industrial uses.

Specifications of Hydrous Benzoyl Peroxide USP Grade
C14H10O4 (anhydrous) --- 242.23
Peroxide, dibenzoyl.
Benzoyl peroxide --- CAS 94-36-0.

Hydrous Benzoyl Peroxide contains not less than 65.0 percent and not more than 82.0 percent of C14H10O4. It contains about 26 percent of water for the purpose of reducing flammability and shock sensitivity.
Caution: Hydrous Benzoyl Peroxide may explode at temperatures higher than 60C or cause fires in the presence of reducing substances. Store it in the original container, treated to reduce static charges.

Packaging and storage: Store in the original container, at room temperature. [NOTE—Do not transfer Hydrous Benzoyl Peroxide to metal or glass containers fitted with friction tops. Do not return unused material to its original container, but destroy it by treatment with sodium hydroxide solution (1 in 10) until addition of a crystal of potassium iodide results in no release of free iodine.]
Identification:
A: Chromatograph Comparision to pass the test.
B: To pass the test.
Assay: Place about 300 mg of previously mixed Hydrous Benzoyl Peroxide in an accurately weighed conical flask fitted with a ground-glass stopper, and weigh again to obtain the weight of the test specimen. Add 30 mL of glacial acetic acid, previously sparged with carbon dioxide for not less than 2 minutes just before use, and swirl the flask gently to effect solution. Add 5 mL of potassium iodide solution (1 in 2), and mix. Allow the solution to stand for 1 minute. Titrate the liberated iodine with 0.1 N sodium thiosulfate. As the endpoint is approached add 1 drop of starch iodide paste, or equivalent, and continue the titration to the discharge of the blue color. Perform a blank determination, and make any necessary correction. Each mL of 0.1 N sodium thiosulfate is equivalent to 12.11 mg of C14H10O4.

Specifications of Hydrous Benzoyl Peroxide BP Ph Eur Grade
C14H10O4 --- 242.2 --- CAS 94-36-0
Action and use: Used topically in the treatment of acne.

DEFINITION
Content:
dibenzoyl peroxide : 70.0 per cent to 77.0 per cent;
water: minimum 20.0 per cent.

CHARACTERS
Appearance: White or almost white, amorphous or granular powder.
Solubility: Practically insoluble in water, soluble in acetone, soluble in methylene chloride with the separation of water, slightly soluble in ethanol (96 per cent).
It loses water rapidly on exposure to air with a risk of explosion.
Mix the entire sample thoroughly before carrying out the following tests.

IDENTIFICATION
First identification B.
Second identification A, C, D.
A. Ultraviolet and visible absorption spectrophotometry.
B. Infrared absorption spectrophotometry. Comparison Ph. Eur. reference spectrum of hydrous benzoyl peroxide.
C. Dissolve about 25 mg in 2 mL of acetone. Add 1 mL of a 10 g/L solution of diethylphenylenediamine sulfate and mix. A red colour develops which quickly darkens and becomes dark violet within 5 min.
D. To 1 g add 5 mL of ethanol (96 per cent), 5 mL of dilute sodium hydroxide solution and 10 mL of water. Boil the mixture under reflux for 20 min. Cool. The solution gives reaction of benzoates.

TESTS
Acidity: Dissolve a quantity of the substance to be examined containing the equivalent of 1.0 g of dibenzoyl peroxide in 25 mL of acetone, add 75 mL of water and filter. Wash the residue with two quantities, each of 10 mL, of water. Combine the filtrate and the washings and add 0.25 mL of phenolphthalein solution. Not more than 1.25 mL of 0.1 M sodium hydroxide is required to change the colour of the indicator. Carry out a blank test.
Related substances: To pass the test.
Chlorides: Maximum 0.4 per cent.

Benzoyl Peroxide SDS, Safety Data Sheet
MSDS, Material Safety Data Sheet 24-Jun-21

Product Name & Other Names: Benzoyl Peroxide or Dibenzoyl peroxide. Hydrous Benzoyl Peroxide.
CAS No.: 94-36-0
EINECS EC Number: 202-327-6
Molecular Weight: 242.23
Chemical Formula: (C6H5CO)2O2
Relevant uses and uses advised against (if any): Laboratory and Industrial Use.
Supplier: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Organic peroxides (Type C), H242
Skin sensitization (Category 1), H317
Eye irritation (Category 2), H319
Hazardous to aquatic environment (Category 3), H402

Hazard Statements:
H242 - Heating may cause a fire.
H317 - May cause an allergic skin reaction
H319 - Causes serious eye irritation
H402 - Harmful to aquatic life.

Precautionary Statements - Prevention
P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P220: Keep/Store away from clothing/combustible materials
P221: Take any precaution to avoid mixing with combustibles
P261: Avoid breathing dust.
P234: Keep only in original container.
P264: Wash face, hands and any exposed skin thoroughly after handling
P270: Do not eat, drink or smoke when using this product
P271: Use only outdoors or in a well-ventilated area
P273: Avoid release to the environment.
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection.

Precautionary Statements - Response
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of water.
P304 + P341: IF INHALED: If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P314: Get Medical advice/attention if you feel unwell.
P330: If swallowed, rinse mouth.
P333 + P313: If skin irritation or rash occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/ attention
P342 + P311: If experiencing respiratory symptoms: Call a POISON CENTER or doctor.
P362: Take off contaminated clothing and wash before reuse.
P370 + P378: In case of fire: Use water for extinction
Precautionary Statements - Storage
P402: Store in a dry place.
P403 + P233 - Store in a well-ventilated place. Keep container tightly closed
P501: Dispose of contents/container in accordance with local, regional, national, international regulations.
Supplemental Hazard information (EU)
EUH001 Explosive when dry.

Product Name & Other Names: Benzoyl Peroxide or Dibenzoyl peroxide. Hydrous Benzoyl Peroxide.
CAS No.: 94-36-0
EINECS EC Number: 202-327-6

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: If swallowed, do not induce vomiting. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately.
Skin Contact: In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Cover the irritated skin with an emollient. Cold water may be used. Wash clothing & shoes before reuse. Get medical attention.
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention.

Fire: Not combustible, but substance is a strong oxidizer and its heat of reaction with reducing agents or combustibles may cause ignition. Heating or contact with water releases oxygen which may intensify combustion in an existing fire. It is explosive when dry.
Explosion: An explosion hazard when mixed with finely powdered organic matter, metal powder, or reducing agents.
Special hazards arising from the substance or mixture: Carbon oxides and fumes.
Fire Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical, or carbon dioxide. Use means suitable for extinguishing surrounding fire. Cool containers with flooding quantities of water until well after fire is out.
Extinguishing Media Not recommended: Avoid using solid water jet as it may scatter the fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment cleanup procedures and Storage: It is an oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing etc.). Keep the substance damp using water spray. Do not touch spilled material. Prevent entry into sewers. Eliminate all ignition sources. Avoid penetration into waterways, sewers, soil, or groundwater. Local authorities should be advised if significant spillages cannot be contained.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like reducing agents, organic material, water, and powdered metals especially aluminum, acids, bases, halides, oxidizing agents, combustible materials. Avoid breathing dust. Handle product only in closed system or provide appropriate exhaust ventilation at machinery. Organic peroxides and self-reacting hazardous materials. Recommended storage temperature 2C - 8C.

Airborne Exposure Limits: Contains no substances with occupational exposure limit values.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g., lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: Solid
Odor: Bitter almond-like
Odor threshold: Not available.
pH: Not available.
Relative density: 0.53
Melting Point: 103C - 104C
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: 80C
Decomposition temperature: >70C.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Practically insoluble in water
Viscosity: Not available.

Stability: Stable under recommended conditions of use and storage.
Hazardous Decomposition Products: Burning may produce Carbon oxide. Oxygen is released which supports combustion.
Hazardous Polymerization: Will not occur
Incompatibilities: Reducing agents, organic material, water, and powdered metals, especially aluminum. Acids, Bases, Halides, Oxidizing agents, Strong reducing agents, Combustible materials.
Conditions to Avoid: Combustible materials and incompatibles. Heat, flames, and sparks.

Oral rat LD50: 7710 mg/kg
LC50 rat: > 24.3 mg/l; 4 h
Carcinogenicity: IARC: 3 - Group 3: Not classifiable as to its carcinogenicity to humans (Benzoyl peroxide).
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

Toxicity to fish LC50: No data available
Mobility: No information available.
Persistence and degradability: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state, and local requirements.

Land Transport DOT USA, TDG Canada and ADR/RID Europe
Proper Shipping Name: ORGANIC PEROXIDE TYPE C, SOLID (DIBENZOYL PEROXIDE)
Hazard Class: 5.2; UN/NA: UN3104
Sea Transport I.M.O/IMDG & Air Transport ICAO/IATA
Proper Shipping Name: ORGANIC PEROXIDE TYPE C, SOLID (DIBENZOYL PEROXIDE)
Hazard Class: 5.2; UN/NA: UN3104

USA:
California Proposition 65: Not listed.
SARA 311/312 Hazards: See section 2.

Hydrous Benzoyl Peroxide Manufacturers, Suppliers, Exporters, Wholesellers:

Plot No. 2900/46&47 + 2900/163to167, GIDC, Ankleshwar, Dist. Bharuch, India
India, USA, UAE
TEL: (Office) 91-22-23774610, 91-22-23723564

If I give you “My Word” Nobody can undo it.
If I sign an “Agreement” my Lawyer will undo it

Our products are for industrial and laboratory use only. The user must test the material before use. We are not dispensing chemists or druggist and do not offer over the counter type (OTC) products for medical use by individuals.

Specifications, Properties, Uses, SDS of Hydrous Benzoyl Peroxide USP BP Ph Eur Grade Manufacturer Supplier Exporter Wholesale & Small Packs, CAS Number 94-36-0.

Hydrous Benzoyl Peroxide Manufacturers, Suppliers, Exporters, Wholesellers: