Specifications, Uses, SDS of Tertiary Butyl Hydroperoxide Manufacturers

	King of Chemicals
Specifications, Properties, Uses, SDS of TBHP Tert or Tertiary Butyl Hydroperoxide Manufacturer Supplier Exporter Wholesale & Small Packs, CAS Number 75-91-2.
King of Chemicals has several associated companies having accreditations like cGMP, GLP - FDA Approved Good Manufacturing Practice and Good Laboratory Practice of WHO standard, ISO-9001, ISO-14001, ISO/IEC 17025, ISO ISO-45000, HACCP, FSSC 220000, FSSAI, "REACH" Registered, Kosher & Halal Certified. DMF support can be made available if needed. We offer USP NF BP Ph Eur EP IP JP Analytical Reagent FCC Food Grade Chemicals & Nutraceuticals.

Muby Chem Pvt. Ltd. is a several decades old group of companies, engaged in manufacturing, supplying, distributing, wholesale supplies of TBHP Tert or Tertiary Butyl Hydroperoxide for actual users, including retail or small pack supplies for research and development work.

We supply fine and speciality chemicals, pharmaceutical excipients, mineral fortifiers in chemically pure, analytical reagent grade, IP BP USP Ph Eur EP JP and other pharmaceutical grade monograph including FCC Food grade chemicals and Nutraceuticals at best prices. We and/or our associated units have all the facilities to supply as per cGMP standard observing good manufacturing practice and good laboratory practice. We can assure low microbial count and also offer a test certificate for the same. We maintain warehouses across USA, India, and UAE. Our group exports to USA, Canada, Mexico, Argentina, Brazil, Chile, Korea, Malaysia, Thailand, Indonesia, Europe, and several other parts of the world. We supply in wholesale container loads to small pack of few grams. Solid products may be specified for it size and shape as desired by the buyer.

The Properties, Specifications, Monograph and Uses of TBHP Tert or Tertiary Butyl Hydroperoxide:

Tertiary Butyl Hydroperoxide or TBHP or Tert-Butyl hydroperoxide: CAS Number: 75-91-2, EINECS EC Number: 200-915-7, Molecular Formula: C4H10O2 or (CH3)3COOH, Molecular Weight: 90.12, HS Code 29096000

tert-Butyl hydroperoxide or Tertiary Butyl Hydroperoxide or TBHP is the organic compound with the formula (CH3)3COOH. It is a hydroperoxide, in fact one of the most widely used in a variety of oxidation processes, for example the Halcon process. It is normally supplied as a 69% to 70% aqueous solution. Compared to hydrogen peroxide and organic peracids, tert-butyl hydroperoxide is less reactive, more soluble in organic solvents. Overall, it is renowned for the convenient handling properties of its solutions. Its solutions in organic solvents are highly stable. Industrially, tert-butyl hydroperoxide is used to prepared propylene oxide. In the Halcon process. On a small scale, tert-butyl hydroperoxide is used to produce some fine chemicals by the Sharpless epoxidation. A solution of tert-butyl hydroperoxide and water with a concentration of greater than 90% is forbidden to be shipped according to US Department of Transportation Hazardous Materials Table 49 CFR 172.101.

Tertiary Butyl Hydroperoxide or TBHP, SDS GHS, Safety Data Sheet
MSDS, Material Safety Data Sheet 08-Aug-21

Product Name & Other Names: Tertiary Butyl Hydroperoxide or TBHP or Tert-Butyl hydroperoxide.
CAS No.: 75-91-2
EINECS EC No.: 200-915-7
Molecular Formula: C4H10O2 or (CH3)3COOH
Molecular Weight: 90.12
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Supplier: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP):

Flammable liquids (Category 3) H226
Organic peroxides (Type F), H242
Acute toxicity, Oral (Category 4) H302
Acute toxicity, Inhalation (Category 3) H331
Acute toxicity, Dermal (Category 3) H311
Skin corrosion (Category 1C), H314
Skin sensitization (Category 1), H317
Germ cell mutagenicity (Category 2), H341
Chronic aquatic toxicity (Category 2), H411

Hazard statements:
H226: Flammable liquid and vapor.
H242: Heating may cause a fire.
H302: Harmful if swallowed.
H331: Toxic if inhaled.
H314: Causes severe skin burns and eye damage.
H317: May cause an allergic skin reaction.
H341: Suspected of causing genetic defects.
H411: Toxic to aquatic life with long lasting effects.

Precautionary statements:
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical/ventilating/light/…/equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P264: Wash … thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P330: Rinse mouth.
P362: Take off contaminated clothing and wash before reuse.
P391: Collect spillage.
P301+310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302+352: IF ON SKIN: Wash with soap and water.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P309 + P310 IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician.
P370+378: In case of fire: Use Water spray, Carbon dioxide (CO2), Foam, Dry powder, and Sand for extinction.
P403+233+235: Store in a well-ventilated place. Keep container tightly closed. Keep cool.
P405: Store locked up.
P501: Dispose of contents/container to authorized agents only.

Product Name & Other Names: Tertiary Butyl Hydroperoxide or TBHP or Tert-Butyl hydroperoxide.
CAS No.: 75-91-2
EINECS EC No.: 200-915-7
Percentage: Around 70% in water.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Note to physicians: Treat symptomatically.

Flammability of the Product: Flammable.
Auto-Ignition Temperature: SADT: 88C.
Flash Points: 42C
Products of Combustion: Carbon dioxide, Carbon monoxide, fumes.
Fire: Inflammable.
Explosion: Explosive in presence of heat.
Fire Extinguishing Media: Use Water spray, Carbon dioxide (CO2), Foam, Dry powder, and Sand for extinction. Flammable liquid and vapor. Vapors are heavier than air and may travel to a source of ignition and flash back. Vapors can spread along the ground and collect in low or confined areas. Never direct a water jet in the container to prevent any splashing of the product which could cause spreading of the fire. Cool containing vessels with water jet to prevent pressure build-up, auto-ignition, or explosion.
Extinguishing Media Not recommended: Avoid using solid water jet as it may scatter the fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment cleanup procedures and Storage: Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Remove all sources of ignition. Provide proper ventilation. If liquid - absorb the material on a porous, inert material such as earth, sand, or vermiculite. Carefully sweep solid/powder up the material without causing dust. Dispose of in accordance with local regulations.
Large liquid spillages should be contained by use of sand or another inert material. The spillage should be transferred to a suitable container and recovered or disposed of in accordance with local regulations. Because of the danger of spontaneous combustion, any combustible material, such as cloth, used for cleaning spillages, should be saturated with water, and disposed of promptly, preferably by incineration.

Precautions for safe handling: Do not ingest. Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like heat, strong oxidizing agents, strong reducing agents, strong acids, strong bases, powdered metals, organic materials.
Keep in a tightly closed container, stored in a cool, dry, ventilated area. Keep the product in its original container well sealed, in a dry and ventilated area, away from potential sources of ignition and protected from light. Protect against physical damage. Recommended storage temperature 2C - 8C.

Airborne Exposure Limits: Not Established. TWA: 0.1 ppm Skin ACGIH TLV
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full-face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: Clear colorless liquid.
Odor: Characteristic.
Odor threshold: Not available.
pH: around 5.
Relative density: 0.9 to 0.94
Melting point/freezing point: -3C.
Initial boiling point and boiling range: 89C to 96C.
Flash point: 42C.
Auto-ignition temperature: SADT: 88C.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility(ies): Soluble in water.
Viscosity: Not available.
Molecular Formula: C4H10O2 or (CH3)3COOH
Molecular Weight: 90.12

Stability: Stable under ordinary conditions of use and storage. Vapor/air-mixtures are explosive at intense warming. Violent reactions possible with: Strong acids, alkalis, reducing agents, metallic salts.
Hazardous Decomposition Products: It emits Carbon dioxide, Carbon monoxide & Toxic Fumes.
Hazardous Polymerization: Will not occur.
Incompatibilities: Heat, strong oxidizing agents, strong reducing agents, strong acids, strong bases. Powdered metals, Organic materials.
Conditions to Avoid: Incompatibles, oxidizing agents, strong alkalis, strong acids, heat & light.

Carcinogenicity: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology: No information found
Teratogenicity: No information found
Reproductive Effects: No information found
Mutagenicity: No information found
Neurotoxicity: No information found.

Toxicity to fish: No information available.
Persistence and Degradability: Soluble in water Persistence is unlikely.
Bioaccumulation/ Accumulation: No information available.
Mobility: Will likely be mobile in the environment due to its water solubility.
Results of PBT and vPvB assessment: No data available for assessment.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state, and local requirements.

Land Transport DOT USA, TDG Canada & ADR/RID Europe:
UN Number: UN3109
Shipping Name: ORGANIC PEROXIDE TYPE F, LIQUID (tert-BUTYL HYDROPEROXIDE)
Hazard Class: 5.2(8); Packing Group: NA.
Sea Transport IMDG/IMO:
UN Number: UN3109
Shipping Name: ORGANIC PEROXIDE TYPE F, LIQUID (tert-BUTYL HYDROPEROXIDE)
Hazard Class: 5.2(8); Packing Group: NA.
Air Transport IATA/ICAO:
UN Number: UN3109
Shipping Name: ORGANIC PEROXIDE TYPE F, LIQUID (tert-BUTYL HYDROPEROXIDE)
Hazard Class: 5.2(8); Packing Group: NA.

USA:
California Proposition 65: Not listed.
SARA 311/312 Hazards: Fire Hazard, Immediate Health Hazard. See section 2.

TBHP Tert or Tertiary Butyl Hydroperoxide Manufacturers, Suppliers, Exporters, Wholesalers:

Plot No. 2900/46&47 + 2900/163to167, GIDC, Ankleshwar, Dist. Bharuch, India
India, USA, UAE
TEL: (Office) 91-22-23774610, 91-22-23723564

If I give you “My Word” Nobody can undo it.
If I sign an “Agreement” my Lawyer will undo it

Our products are for industrial and laboratory use only. The user must test the material before use. We are not dispensing chemists or druggist and do not offer over the counter type (OTC) products for medical use by individuals.

GHS Label Elements Toxic	GHS Label Elements Flammable	GHS Label Elements Health Hazard
GHS Label Elements Corrosive	GHS Label Elements Marine Pollutant

Specifications, Properties, Uses, SDS of TBHP Tert or Tertiary Butyl Hydroperoxide Manufacturer Supplier Exporter Wholesale & Small Packs, CAS Number 75-91-2.

TBHP Tert or Tertiary Butyl Hydroperoxide Manufacturers, Suppliers, Exporters, Wholesalers: