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Specifications, Properties, Uses, SDS of Potassium Iodide USP BP Ph Eur IP Analytical Reagent FCC Food Grade Manufacturer Supplier Exporter Wholesale & Small Packs, CAS Number 7681-11-0.
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Potassium Iodide CAS Number 7681-11-0For Properties Specifications Uses of Potassium Iodide Click Properties, Specifications, Uses, Price, Process of Potassium Iodide Manufacturer.
For For SDS MSDS Sheet of Potassium Iodide Click SDS Safety Data Sheet MSDS Sheet of Potassium Iodide Manufacturer.
The Properties, Specifications, Monograph and Uses of Potassium Iodide:
CAS Number 7681-11-0, EINECS EC Number 231-659-4, HS Code 28276010 or 28276090, Molecular Weight 166, Chemical Formula KI
Potassium iodide is a chemical compound, medication, and dietary supplement. As a medication it is used to treat hyperthyroidism, in radiation emergencies, and to protect the thyroid gland when certain types of radiopharmaceuticals are used. As a supplement it is used in those who have low intake of iodine in the diet. It is on the World Health Organization's List of Essential Medicines, the safest and most effective medicines needed in a health system. Potassium iodide is also used for the iodization of salt. Potassium iodide is used as a nutritional supplement in animal feeds and also in the human diet.
Potassium Iodide USP Grade Specifications:
KI --- 166.00
Potassium iodide CAS 7681-11-0DEFINITION
Potassium Iodide contains NLT 99.0% and NMT 101.5% of KI, calculated on the dried basis.IDENTIFICATION
Iodate:
A. Identification Tests-General, Potassium: Meets the requirements
B. Identification Tests-General, Iodide: Meets the requirements
ASSAY
Procedure
Sample solution: Dissolve 500 mg of Potassium Iodide in 10 mL of water.
Analysis: Add 35 mL of hydrochloric acid to the Sample solution, and titrate with 0.05 M potassium iodate until the dark brown solution that is produced becomes pale brown. Add 2–3 drops of amaranth and continue the titration slowly until the red color just changes to yellow. Each mL of 0.05 M potassium iodate is equivalent to 16.60 mg of KI.
Acceptance criteria: 99.0% to 101.5% on the dried basis.
Iodate solution: Dilute 1 mL of potassium iodate solution (1 in 2500) with water to 100 mL.
Standard solution: Dissolve 100 mg of Potassium Iodide in ammonia- and carbon dioxide-free water and add 1 mL of Iodate solution to obtain 10 mL of solution. Transfer to a color-comparison tube, add 1 mL of starch and 0.25 mL of 1.0 N sulfuric acid, and mix.
Sample solution: Dissolve 1.1 g in sufficient ammonia- and carbon dioxide-free water to obtain 10 mL of solution. Transfer to a color-comparison tube, add 1 mL of starch TS and 0.25 mL of 1.0 N sulfuric acid, and mix.
Acceptance criteria: Any color produced in the Sample solution does not exceed that produced in the Standard solution (NMT 4 µg/g).
Limit of Nitrate, Nitrite, and Ammonia:
Sample solution: Dissolve 1 g in 5 mL of water.
Analysis: To the Sample solution contained in a test tube of 40-mL capacity add 5 mL of 1 N sodium hydroxide and 200 mg of aluminum wire. Insert a pledget of purified cotton in the upper portion of the test tube and place a piece of moistened red litmus paper over the mouth of the tube. Heat the test tube and its contents in a steam bath for 15 min.
Acceptance criteria: No blue coloration of the paper is discernible.
Thiosulfate and Barium:
Sample solution: Dissolve 0.5 g in 10 mL of ammonia- and carbon dioxide-free water.
Analysis: Add 2 drops of 2 N sulfuric acid.
Acceptance criteria: No turbidity develops within 1 min.
Alkalinity:
Sample solution: Dissolve 1.0 g of Potassium Iodide in 10 mL of water.
Analysis: Add 0.1 mL of 0.1 N sulfuric acid and 1 drop of phenolphthalein to the Sample solution.
Acceptance criteria: No color is produced.
Loss on Drying: Dry a sample at 105C for 4 h: it loses NMT 1.0% of its weight.
Packaging and Storage: Preserve in well-closed containers.
Specifications of Potassium Iodide BP Ph Eur Grade
KI -- 166.0 -- CAS 7681-11-0
Content: 99.0 per cent to 100.5 per cent (dried substance).CHARACTERS
Appearance: White or almost white powder or colourless crystals.
Solubility: Very soluble in water, freely soluble in glycerol, soluble in ethanol (96 per cent).IDENTIFICATION
A. Solution S (see Tests) gives the reactions of iodides (2.3.1).
B. Solution S gives the reactions of potassium (2.3.1).TESTS
Solution S: Dissolve 10.0 g in carbon dioxide-free water R prepared from distilled water R and dilute to 100 ml with the same solvent.
Appearance of solution: Solution S is clear and colourless.
Alkalinity: To 12.5 ml of solution S add 0.1 ml of bromothymol blue solution R1. Not more than 0.5 ml of 0.01 M hydrochloric acid is required to change the colour of the indicator.
Iodates: To 10 ml of solution S add 0.25 ml of iodide-free starch solution R and 0.2 ml of dilute sulphuric acid R and allow to stand protected from light for 2 min. No blue colour develops.
Sulphates: Maximum 150 ppm.
Dilute 10 ml of solution S to 15 ml with distilled water R.
Thiosulphates: To 10 ml of solution S add 0.1 ml of starch solution R and 0.1 ml of 0.005 M iodine. A blue colour is produced.
Iron: Maximum 20 ppm.
Dilute 5 ml of solution S to 10 ml with water R.
Heavy metals: Maximum 10 ppm.
12 ml of solution S complies with test A. Prepare the reference solution using lead standard solution (1 ppm Pb) R.
Loss on drying: Maximum 1.0 per cent, determined on 1.00 g of previously powdered substance by drying in an oven at 105C for 3 h.
Specifications of Potassium Iodide IP Grade
KI -- Molecular Weight 166.00Category: Antithyroid; antifungal; expectorant.
Description: Colourless crystals or white powder; odourless
Solubility: Very soluble in water; freely soluble in glycerin; soluble in ethanol (95%).STANDARDS
Potassium Iodide contains not less than 99.0 per cent and not more than 100.5 per cent of KI, calculated with reference to the dried substance.
Identification: A 10% w/v solution in carbon dioxide-free water (solution A) gives the reactions of potassium salts and of iodides.
Alkalinity: To 10 ml of solution A add 0.2 ml of 0.01M sulphuric acid; no colour is produced on addition of a drop of PhPh solution. .
Clarity and colour of solution: Solution A is clear and colourless.
Arsenic: Dissolve 5.0 g in 50 ml of 'water and 12 ml of stannated hydrochloric acid AsT. The resulting solution complies with the limit test for arsenic (2 ppm).
Heavy metals: Not more than 10 ppm, determined on 2.0 g
Iron: Solution A complies with the limit lest for iron (20 ppm).
Barium: Dissolve 0.5 g in 10 ml of water and add 1 ml of dilute sulphuric acid; no turbidity develops within one minute.
Specifications of Potassium Iodide FCC Food Grade
KI Formula wt 166.00
CAS: 7681-11-0DESCRIPTION
Potassium Iodide occurs as hexahedral crystals, either transparent and colorless or somewhat opaque and white, or as a white, granular powder. It is stable in dry air but slightly hygroscopic in moist air. One gram is soluble in 0.7 mL of water at 25C, in 0.5 mL of boiling water, in 2 mL of glycerin, and in 22 mL of alcohol.REQUIREMENTS
Identification:
A. A 1:10 aqueous solution responds to the tests for Potassium and for Iodide.
B. The pH of a 1:20 aqueous solution is between 6 and 10.
Assay: Not less than 99.0% and not more than 101.5% of KI after drying.
Iodate: Not more than 4 mg/kg.
Lead: Not more than 4 mg/kg.
Loss on Drying: Not more than 1%.
Nitrate, Nitrite, and Ammonia: Passes test.
Thiosulfate and Barium: Passes test.
Specifications of Potassium Iodide Analytical Reagent Grade
KI -- Formula Weight 166.00
CAS Number 7681-11-0REQUIREMENTS
Assay: Minimum 99.0% KI
pH of a 5% solution: 6.0-9.2 at 25CMAXIMUM ALLOWABLE
Insoluble matter: 0.005%
Loss on drying at 150C: 0.2%
Chloride and bromide (as Cl): 0.01%
Iodate (IO3): 3 ppm
Nitrogen compounds (as N): 0.001%
Phosphate (PO4): 0.001%
Sulfate (SO4): 0.005%
Barium (Ba): 0.002%
Heavy metals (as Pb): 5 ppm
Iron (Fe): 3 ppm
Calcium (Ca): 0.002%
Magnesium (Mg): 0.001%
Sodium (Na): 0.005%
The MSDS-SDS Hazard Statement of Potassium Iodide:
Potassium Iodide SDS, Safety Data Sheet
MSDS, Material Safety Data Sheet 04-Jul-211. Product Identification
Product Name & Other Names: Potassium iodide or Knollide or Potide or Iodic acid potassium salt or Hydroiodic acid potassium salt.
CAS No.: 7681-11-0
EINECS EC Number: 231-659-4
Molecular Weight: 166
Chemical Formula: KI
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008Acute toxicity, Oral (Category 4), H302
Skin irritation (Category 2), H315
Eye irritation (Category 2), H319Labeling according to GHS & Regulation (EC) No 1272/2008
GHS Label Elements
IrritantSignal Words: Warning
Hazard statements:
H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.Precautionary statements:
P264: Wash … thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P330: Rinse mouth.
P362: Take off contaminated clothing and wash before reuse.
P301+312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+352: IF ON SKIN: Wash with soap and water.
P332+313: If skin irritation occurs: Get medical advice/attention.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.
P501: Dispose of contents/container to authorized agents only.3. Composition/Information on Ingredients
Product Name & Other Names: Potassium iodide or Knollide or Potide or Iodic acid potassium salt or Hydroiodic acid potassium salt.
CAS No.: 7681-11-0
EINECS EC Number: 231-659-44. First Aid Measures
Always seek medical attention after first aid measures are provided.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.5. Fire Fighting Measures
Flammability of the Product: Non-flammable.
Products of Combustion: Hydrogen Iodide, Iodine, Oxides of Potassium etc..
Fire: Not considered to be a fire hazard.
Explosion: Not an Explosive item.
Fire Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical, or carbon dioxide. Use any means suitable for extinguishing surrounding fire.
Extinguishing Media Not recommended: None specified.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place. On decomposition it may emit hydrogen iodide. Containers may explode on heating.6. Accidental Release Measures
Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment cleanup procedures and Storage: Contain spilled material. Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow evacuating as per law.7. Handling and Storage
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, chlorinated compounds, metals & acids.8. Exposure Controls/Personal Protection
Airborne Exposure Limits: USA ACGIH, ACGIH TWA (ppm): 0.01 ppm Inhalable fraction
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full-face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.9. Physical and Chemical Properties
Appearance: Colorless white powder or crystals.
Odor: It is odorless.
Odor threshold: Not available.
pH: 6-9.
Relative density: around 3.13
Boiling Point: 1330C 2426F.
Melting Point: 681C 1257F.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: It is freely soluble in water. 76 parts in 100 parts water @ 25 deg. C
Viscosity: Not available.
Molecular formula: KI
Molecular weight: 16610. Stability and Reactivity
Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits toxic iodide or hydrogen iodide fumes when heated to decomposition. It may form potassium oxide and hydrogen iodide and iodide.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents, chlorinated compounds, metals & acids.
Conditions to Avoid: Incompatibles, heat, light, and moisture.11. Toxicological Information
LD50 Oral - mouse - 1000 mg/kg
LD50 Oral - Rat - 2799 mg/kg
Carcinogenic Effects: Not a reported carcinogen by IARC NTP ACGIH OSHA.
Mutagenic Effects: Mutagenic for mammalian somatic cells. Investigated as a mutagen, reproductive effector.
Teratogenic Effects: Iodine salts can cause deformity, illness, and death of a fetus.
Developmental Toxicity: Not available.12. Ecological Information
Toxicity to fish: LC50 - Oncorhynchus mykiss (rainbow trout) - 2.190 mg/l - 96 h
Toxicity to daphnia and other aquatic invertebrates: EC50 - Daphnia - 2,7 mg/l - 24 h
Persistence and Degradability: Unlikely to persist due to water solubility.
Mobility: Mobile due to water solubility.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state, and local requirements.
14. Transport Information
Land Transport DOT USA, TDG Canada & ADR/RID Europe: Not regulated.
Sea Transport IMDG/IMO: Not regulated.
Air Transport IATA/ICAO: Not regulated.15. Regulatory Information
USA:
SARA 311/312 Hazards: Immediate (acute) health hazard Delayed (chronic) health hazard.
California Prop.65: Not Listed.16. Other Information
DISCLAIMER: The information and recommendations set forth herein are presented in good faith and believed correct as of the date hereof. It is compiled from various sources, and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules, or insurance requirements applicable. This SDS MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a professionally trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. This shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. In no case shall our company be liable to loss or damages by the product user.
Potassium Iodide Manufacturers, Suppliers, Exporters, Wholesalers:
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TEL: (Office) 91-22-23774610, 91-22-23723564e-mail: info@kingofchemicals.com
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