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Specifications, Properties, Uses, SDS of Undecylenic acid or Undecenoic acid USP BP Ph Eur Food Grade Manufacturer Supplier Exporter Wholesale & Small Packs, CAS Number 112-38-9.
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Undecylenic acid or Undecenoic acid CAS Number 112-38-9For Properties Specifications Uses of Undecylenic acid or Undecenoic acid Click Properties, Specifications, Uses, Price, Process of Undecylenic acid or Undecenoic acid Manufacturer.
For For SDS MSDS Sheet of Undecylenic acid or Undecenoic acid Click SDS Safety Data Sheet MSDS Sheet of Undecylenic acid or Undecenoic acid Manufacturer.
The Properties, Specifications, Monograph and Uses of Undecylenic acid or Undecenoic acid:
CAS Number: 112-38-9, EINECS EC Number: 203-965-8, Molecular Formula: CH2=CH(CH2)8COOH, Molecular Weight: 184.28, HS Code ---**
Undecylenic acid is an organic compound with the formula CH2=CH(CH2)8CO2H. It is an unsaturated fatty acid. It is a colorless oil. Undecylenic acid is used in the treatment of fungal infections of the skin, but it is also a precursor in the manufacture of many pharmaceuticals, personal hygiene products, cosmetics, and perfumes. Undecylenic acid is approved by the USA FDA for topical route and is listed in the Code of Federal Regulations.
Undecylenic Acid USP Grade Specifications:
C11H20O2 --- 184.28
10-Undecenoic acid.
10-Undecenoic acid CAS 112-38-9Undecylenic Acid contains not less than 97.0 percent and not more than 100.5 percent of C11H20O2.
Packaging and storage: Preserve in tight, light-resistant containers.
Identification:
A: To 1 mL add potassium permanganate TS, dropwise: the permanganate color is discharged.
B: Place 3 mL of it and 3 mL of freshly distilled aniline in a tall test tube, and heat for 10 minutes at a rate such that the ring of condensate remains just below the mouth of the tube. Cool, add 10 mL of alcohol and 10 mL of ether, and transfer to a separator. Wash the ether solution with four 20-mL portions of water and discard the water washings. Heat on a steam bath until the odor of ether no longer is perceptible, then add a few mg of activated carbon, mix, and filter. Evaporate the filtrate nearly to dryness and recrystallize the residue from 70 percent alcohol: the anilide so obtained melts between 66C and 67.5C.
Specific gravity: between 0.910 and 0.913.
Congealing range: not lower than 21C.
Refractive index: between 1.447 and 1.448.
Residue on ignition: not more than 0.15%.
Water-soluble acids: Shake 5 mL with 5 mL of water and filter the water layer through a filter paper previously moistened with water. Add 1 drop of methyl orange and titrate with 0.01 N sodium hydroxide VS: not more than 1.0 mL of 0.010 N sodium hydroxide is required to match the color produced by 1 drop of methyl orange in 5 mL of water.
Iodine value: between 131 and 138.
Assay: Dissolve about 750 mg of Undecylenic Acid, accurately weighed, in 50 mL of alcohol, add 3 drops of phenolphthalein, and titrate with 0.1 N sodium hydroxide to the first pink color that persists for not less than 30 seconds. Perform a blank determination and make any necessary correction. Each mL of 0.1 N sodium hydroxide is equivalent to 18.43 mg of C11H20O2.
Specifications of Undecenoic Acid BP Grade, Ph Eur:
C11H20O2 --- 184.3 --- CAS 112-38-9DEFINITION
Undec-10-enoic acid.
Content: 97.0 per cent to 102.0 per cent.CHARACTERS
Appearance: White or very pale yellow, crystalline mass or colourless or pale-yellow liquid.
Solubility: Practically insoluble in water, freely soluble in ethanol (96 per cent) and in fatty and essential oils.IDENTIFICATION
A. Refractive index: 1.447 to 1.450, determined at 25±0.5C.
B. Freezing point: 21C to 24C.
C. To 2.0 g add 2 mL of freshly distilled aniline and boil under a reflux condenser for 10 min. Allow to cool and add 30 mL of ether. Shake with 3 quantities, each of 20 mL, of dilute hydrochloric acid and then with 20 mL of water. Evaporate the organic layer to dryness on a water-bath. After re-crystallising twice from ethanol (70 per cent V/V) and drying in vacuo for 3 h, the residue melts at 66C to 68C.
D. Dissolve 0.1 g in a mixture of 2 mL of dilute sulfuric acid and 5 mL of glacial acetic acid. Add dropwise 0.25 mL of potassium permanganate solution. The colour of the potassium permanganate is discharged.TESTS
Peroxide value: Maximum 10.
Fixed and mineral oils: To 1.0 g add 5 mL of sodium carbonate solution and 25 mL of water and boil for 3 min. The hot solution is not more opalescent than reference suspension.
Water-soluble acids: To 1.0 g add 20 mL of water heated to 35-45C and shake for 2 min. Cool and filter the aqueous layer through a moistened filter. To 10 mL of the filtrate add 0.1 mL of phenolphthalein solution. Not more than 0.1 mL of 0.1 M sodium hydroxide is required to change the colour of the indicator.
Degree of unsaturation: Dissolve 85.0 mg in a mixture of 5 mL of dilute hydrochloric acid and 30 mL of glacial acetic acid. Using 0.05 mL of indigo carmine solution as indicator, added towards the end of the titration, titrate with0.0167 M bromide-bromate until the colour changes from blue to yellow. 8.9 mL to 9.4 mL of0.0167 M bromide-bromate is required. Carry out a blank titration.
Sulphated ash: Maximum 0.1 per cent, determined on 0.50 g.
The MSDS-SDS Hazard Statement of Undecylenic Acid:
Undecylenic Acid or Undecenoic Acid SDS, Safety Data Sheet
MSDS, Material Safety Data Sheet 19-Aug-211. Product Identification
Product Name & Other Names: Undecylenic Acid or Undecenoic Acid
CAS No.: 112-38-9
EINECS EC Number: 203-965-8
Molecular Formula: CH2=CH(CH2)8COOH
Molecular Weight: 184.28
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP)Skin irritation Category 2, H315
Serious eye damage/eye irritation Category 2A, H319
Specific target organ toxicity - single exposure, Respiratory system. Category 3, H335
Long-term (chronic) aquatic hazard Category 3, H412Labeling Regulation EC 1272/2008 (CLP) & GHS
GHS Label Elements
IrritantSignal Words: Warning
Hazard statements:
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H412 Harmful to aquatic life with long lasting effects.Precautionary statements:
P264: Wash … thoroughly after handling.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P332+P313: If skin irritation occurs: Get medical advice/attention.
P337+P313: If eye irritation persists: Get medical advice/ attention.
P362: Take off contaminated clothing and wash before reuse.3. Composition/Information on Ingredients
Product Name & Other Names: Undecylenic Acid or Undecenoic Acid
CAS No.: 112-38-9
EINECS EC Number: 203-965-84. First Aid Measures
Always seek medical attention after first aid measures are provided.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen and get medical attention immediately.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention. Wash clothing and shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.5. Fire Fighting Measures
Fire: As with most organic solids, fire is possible at elevated temperatures or by contact with an ignition source.
Product of Combustion: Carbon oxides and fumes.
Explosion: Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard.
Fire Extinguishing Media: Water spray, dry chemical, alcohol foam, or carbon dioxide.
Extinguishing Media Not recommended: Avoid using solid water jet as it may scatter the fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.6. Accidental Release Measures
Personal precautions, protective equipment and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil or water sources.
Methods and materials used for containment cleanup procedures and Storage: Corrosive solid. Contain spilled material. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all ignition sources.7. Handling and Storage
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat or smoke while handling. Avoid contact with skin, eyes and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like bases, oxidizing agents, reducing agent. Containers may be hazardous when empty since they retain product residues.8. Exposure Controls/Personal Protection
Airborne Exposure Limits: This product does not contain any hazardous materials with occupational exposure limits established by the region-specific regulatory bodies.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g., lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or full-face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.9. Physical and Chemical Properties
Appearance: Light yellow or white.
Odor: Sweet.
Odor threshold: Not available.
pH: Not available.
Relative density: 0.9
Boiling Point: 275C literature.
Melting Point: 21-24C.
Flash point: 148C.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor Density (Air=1): Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Insoluble in water.
Viscosity: Not available.
Molecular Formula: CH2=CH(CH2)8COOH
Molecular Weight: 184.2810. Stability and Reactivity
Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Fumes, carbon dioxide and carbon monoxide may form when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Bases, Oxidizing agents, Reducing agent.
Conditions to Avoid: Heat, dusting and incompatibles.11. Toxicological Information
Oral rat LD50: 2500 mg/Kg
Oral rabbit LD50: >5000 mg/Kg
Carcinogenicity: This product is not classifiable as to its carcinogenicity based on its IARC, ACGIH, NTP, or EPA classification.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.12. Ecological Information
Toxicity to fish: No information available.
Persistence and Degradability: No information available.
Mobility: No information available.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused material in accordance with legal requirements.
14. Transport Information
Land Transport DOT USA, TDG Canada & ADR/RID Europe: Not Regulated.
Sea Transport IMDG/IMO: Not Regulated.
Land Transport IATA/ICAO: Not Regulated.15. Regulatory Information
USA:
SARA 313: Not applicable.
SARA 311/312 Hazard Categories: See section 2 for more information.Section 16 - Additional Information
DISCLAIMER: The information and recommendations set forth herein are presented in good faith and believed correct as of the date hereof. It is compiled from various sources, and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules, or insurance requirements applicable. This SDS MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a professionally trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. This shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. In no case shall our company be liable to loss or damages by the product user.
Undecylenic acid or Undecenoic acid Manufacturers, Suppliers, Exporters, Wholesalers:
King of Chemicals manufacturers
Plot No. 2900/46&47 + 2900/163to167, GIDC, Ankleshwar, Dist. Bharuch, India
India, USA, UAE
TEL: (Office) 91-22-23774610, 91-22-23723564e-mail: info@kingofchemicals.com
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