Specifications, Uses, SDS of Titanium Dioxide Manufacturers

	King of Chemicals Manufacturers
Specifications, Properties, Uses, SDS of Titanium Dioxide USP BP Ph Eur FCC Food Grade Manufacturer Supplier Exporter Wholesale & Small Packs, CAS Number 13463-67-7.
King of Chemicals has several associated companies having accreditations like cGMP, GLP - FDA Approved Good Manufacturing Practice and Good Laboratory Practice of WHO standard, ISO-9001, ISO-14001, ISO/IEC 17025, ISO ISO-45000, HACCP, FSSC 220000, FSSAI, "REACH" Registered, Kosher & Halal Certified. e-CTD and DMF support can be made available if needed. We offer USP NF BP Ph Eur EP IP JP Analytical Reagent FCC Food Grade Chemicals & Nutraceuticals.

Muby Chem Pvt. Ltd. is a several decades old group of companies, engaged in manufacturing, supplying, distributing, wholesale supplies of Titanium Dioxide for actual users, including retail or small pack supplies for research and development work.

We supply fine and speciality chemicals, pharmaceutical excipients, mineral fortifiers in chemically pure, analytical reagent grade, IP BP USP Ph Eur EP JP and other pharmaceutical grade monograph including FCC Food grade chemicals and Nutraceuticals at best prices. We and/or our associated units have all the facilities to supply as per cGMP standard observing good manufacturing practice and good laboratory practice. We can assure low microbial count and also offer a test certificate for the same. We maintain warehouses across USA, India, and UAE. Our group exports to USA, Canada, Mexico, Argentina, Brazil, Chile, Korea, Malaysia, Thailand, Indonesia, Europe, and several other parts of the world. We supply in wholesale container loads to small pack of few grams. Solid products may be specified for it size and shape as desired by the buyer.

CAS Number 13463-67-7, EINECS EC Number , Chemical Formula TiO2, Molecular weight 79.87, HS code 28230010

Titanium dioxide, also known as titanium(IV) oxide or titania is the naturally occurring oxide of titanium, chemical formula TiO2. It has a wide range of applications, including paint, sunscreen, pharmaceutical, cosmetic products, and food coloring. When used as a food coloring, it has E number E171.

Titanium Dioxide USP Grade Specifications:
TiO2 --- 79.87
Titanium oxide (TiO2) CAS 13463-67-7

DEFINITION
Titanium Dioxide contains NLT 99.0% and NMT 100.5% of titanium dioxide (TiO2), calculated on the dried basis. If labeled as attenuation grade, then Titanium Dioxide contains NLT 99.0% and NMT 100.5% of TiO2, calculated on the ignited basis. Attenuation grade material may contain suitable coatings, stabilizers, and treatments to assist formulation.
[Note: If labeled as attenuation grade, then all tests and assays are conducted on uncoated, untreated material. For UV attenuation grade, the test for Loss on Drying does not apply. The FDA requires the content of lead to be NMT 10 ppm (µg/g), that of antimony to be NMT 2 ppm (µg/g), and that of mercury to be NMT 1 ppm (µg/g) (21 CFR 73.1575).]

IDENTIFICATION
A.
Sample: 500 mg
Analysis: Add 5 mL of sulfuric acid to the Sample, and heat gently. After fumes of sulfur trioxide appear, continue heating for a minimum of 10 s. Cool the suspension, and cautiously dilute with water to 100 mL. Filter, and to 5 mL of the clear filtrate, add a few drops of hydrogen peroxide.
Acceptance criteria: A yellow-red to orange-red color develops immediately.
ASSAY
To pass the test.
Acceptance criteria: 99.0% to 100.5% on the dried basis; if labeled as attenuation grade, 99.0% to 100.5% on the ignited basis.

Specifications of Titanium Dioxide BP Ph Eur Grade
TiO2 --- 79.9 --- CAS 13463-67-7
Action and use: Protective; excipient.

CHARACTERS
Appearance: White or almost white powder.
Solubility: Practically insoluble in water. It does not dissolve in dilute mineral acids but dissolves slowly in hot concentrated sulphuric acid.

IDENTIFICATION
A. When strongly heated, it becomes pale yellow; the colour disappears on cooling.
B. To 5 ml of solution S2 (see Tests) add 0.1 ml of strong hydrogen peroxide solution R . An orange-red colour appears.
C. To 5 ml of solution S2 add 0.5 g of zinc in granules. After 45 min, the mixture has a violet-blue colour.

TESTS
Solution S1: Shake 20.0 g with 30 ml of hydrochloric acid for 1 min. Add 100 ml of distilled water and heat the mixture to boiling. Filter the hot mixture through a hardened filter paper until a clear filtrate is obtained. Wash the filter with 60 ml of distilled water and dilute the combined filtrate and washings to 200 ml with distilled water.
Solution S2: Mix 0.500 g (m g) with 5 g of anhydrous sodium sulphate in a 300 ml long-necked combustion flask. Add 10 ml of water and mix. Add 10 ml of sulphuric acid and boil vigorously, with the usual precautions, until a clear solution is obtained. Cool, add slowly a cooled mixture of 30 ml of water and 10 ml of sulphuric acid, cool again and dilute to 100.0 ml with water.
Appearance of solution: Solution S2 is not more opalescent than reference suspension and is colourless.
Acidity or alkalinity: Shake 5.0 g with 50 ml of carbon dioxide-free water for 5 min. Centrifuge or filter until a clear solution is obtained. To 10 ml of the solution add 0.1 ml of bromothymol blue solution. Not more than 1.0 ml of 0.01 M hydrochloric acid or 0.01 M sodium hydroxide is required to change the colour of the indicator.
Water-soluble substances: Maximum 0.5 per cent.
Antimony: Maximum 100 ppm.
Arsenic: Maximum 5 ppm.
Barium: To 10 ml of solution S1 add 1 ml of dilute sulphuric acid. After 30 min, any opalescence in the solution is not more intense than that in a mixture of 10 ml of solution S1 and 1 ml of distilled water.
Iron: Maximum 200 ppm.
Heavy metals: Maximum 20 ppm.

Titanium Dioxide FCC Food Grade
TiO2 Formula wt 79.90
INS: 171 CAS: 13463-67-7

DESCRIPTION
Titanium Dioxide occurs as a white, amorphous powder. It is prepared synthetically. It is insoluble in water, in hydrochloric acid, in dilute sulfuric acid, and in alcohol and other organic solvents. It dissolves slowly in hydrofluoric acid and in hot sulfuric acid.
Function: Color.

REQUIREMENTS
Identification: Add 5 mL of sulfuric acid to 500 mg of sample, heat gently until fumes of sulfur trioxide evolve, continue heating for at least 10 s, and cool. Cautiously dilute to about 100 mL with water, and filter. Add a few drops of hydrogen peroxide TS to 5 mL of the clear filtrate. A yellow-red to orange-red color appears immediately.
Assay: Not less than 99.0% and not more than 100.5% of TiO2, after drying and after correcting for any aluminum oxide and/or silicon dioxide found to be present in the sample.
Acid-Soluble Substances: Not more than 0.5%.
Aluminum Oxide and/or Silicon Dioxide: Not more than 2.0%, either singly or combined.
Antimony: Not more than 2 mg/kg.
Arsenic: Not more than 1 mg/kg.
Lead: Not more than 10 mg/kg.
Loss on Ignition: Not more than 0.5% after drying.
Mercury: Not more than 1 mg/kg.
Water-Soluble Substances: Not more than 0.3%.

Titanium Dioxide SDS, Safety Data Sheet
MSDS, Material Safety Data Sheet 22-Aug-21

Product Name & Other Names: Titanium Dioxide or Titanium (IV) Oxide or Titania.
CAS No.: 13463-67-7
EINECS EC Number: 236-675-5
Molecular Weight: 79.87
Chemical Formula: TiO2
Relevant uses and uses advised against (if any): Laboratory Chemicals and Industrial Manufacturing Use.
Supplier: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
This substance is not classified as dangerous according to Directive 67/548/EEC.

Precautionary statements:
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P281: Use personal protective equipment as required.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.

Product Name & Other Names: Titanium Dioxide or Titanium (IV) Oxide or Titania.
CAS No.: 13463-67-7
EINECS EC Number: 236-675-5

Inhalation: Remove to fresh air. Get medical attention for any breathing difficulty.
Ingestion: Not expected to require first aid measures. If large amounts were swallowed, give water to drink and get medical advice.
Skin Contact: Immediately flush skin with plenty of soap and water for at least 15 minutes. Remove contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention if irritation develops.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Get medical attention if irritation persists.

Fire: Not considered to be a fire hazard.
Explosion: Not considered to be an explosion hazard.
Fire Extinguishing Media: It is neither flammable nor explosive. Titanium dioxide may be exposed to water, carbon dioxide, dry chemical, and foam extinguishing agents as necessary during firefighting operations.
Extinguishing Media Not recommended: None specified.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment cleanup procedures and Storage: Do not inhale dust, vapors, mist, or gas. Avoid dust formation. Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g., sand, earth, diatomaceous earth, vermiculite). Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents and metals.

Exposure Limits: This product does not contain any hazardous materials with occupational exposure limits established by the region-specific regulatory bodies. There is a blanket recommendation of 10 mg/m3 for inspirable dusts or mists when limits have not otherwise been established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full-face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: White powder.
Odor: Odorless.
Odor threshold: Not available.
pH: 6 - 7
Relative density: around 4.26
Boiling Point: 2500 - 3000C (4532 - 5432F).
Melting Point: 1855C (3371F).
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Insoluble in water.
Viscosity: Not available.
Molecular Weight: 79.87
Chemical Formula: TiO2

Stability: It is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: No information found.
Hazardous Polymerization: Will not occur.
Incompatibilities: A violent reaction with lithium occurs around 200C (392F) with a flash of light; the temperature can reach 900C. Violent or incandescent reaction may also occur with other metals such as aluminum, calcium, magnesium, potassium, sodium, and zinc.

Toxicological Data:
LD50/rat: > 5,000 mg/kg
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as possible or confirmed human carcinogen by IARC.
NIOSH considers this substance to be a potential occupational carcinogen.
Teratogenic Effects: Not available.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.

Toxicity to fish: LC50/96 h/Pimephales promelas (fathead minnow): > 1,000 mg/l
Acute toxicity to aquatic invertebrates: EC50/LC50 = 1000 mg/L 72 hour
Persistence and Degradability: No information available.
Mobility: No information available.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with legal requirements.

Land Transport DOT USA, TDG Canada & ADR/RID Europe: Not dangerous goods.
Sea Transport IMDG/IMO: Not dangerous goods.
Air Transport IATA/ICAO: Not dangerous goods.

USA Regulations:
SARA 311/312: See section 2.
California Proposition 65: Not listed.

Titanium Dioxide Manufacturers, Suppliers, Exporters, Wholesalers:

Plot No. 2900/46&47 + 2900/163to167, GIDC, Ankleshwar, Dist. Bharuch, India
India, USA, UAE
TEL: (Office) 91-22-23774610, 91-22-23723564

If I give you “My Word” Nobody can undo it.
If I sign an “Agreement” my Lawyer will undo it

Our products are for industrial and laboratory use only. The user must test the material before use. We are not dispensing chemists or druggist and do not offer over the counter type (OTC) products for medical use by individuals.

Specifications, Properties, Uses, SDS of Titanium Dioxide USP BP Ph Eur FCC Food Grade Manufacturer Supplier Exporter Wholesale & Small Packs, CAS Number 13463-67-7.

Titanium Dioxide Manufacturers, Suppliers, Exporters, Wholesalers: