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Specifications, Properties, Uses, SDS of Triethyl Citrate USP NF BP Ph Eur FCC Food Grade Manufacturer Supplier Exporter Wholesale & Small Packs, CAS Number 77-93-0.

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Triethyl Citrate Manufacturer Supplier Exporter
Triethyl Citrate CAS Number 77-93-0

For Properties Specifications Uses of Triethyl Citrate Click Properties, Specifications, Uses, Price, Process of Triethyl Citrate Manufacturer.

For For SDS MSDS Sheet of Triethyl Citrate Click SDS Safety Data Sheet MSDS Sheet of Triethyl Citrate Manufacturer.

The Properties, Specifications, Monograph and Uses of Triethyl Citrate:

Triethyl citrate is used in foods as a flavoring agent, solvent, and surface-active agent Triethyl citrate is an ester of citric acid. It is a colorless, odorless liquid used as a food additive (E number E1505) to stabilize foams, especially as whipping aid for egg white. In pharmaceutical coatings and plastics. Triethyl citrate may also be used in cosmetics, personal care products, pharmaceutical coatings, and plastics.

Specifications of Triethyl Citrate USP NF Grade:
C12H20O7 --- 276.28

DEFINITION
Triethyl Citrate contains NLT 99.0% and NMT 100.5% of C12H20O7 , calculated on the anhydrous basis.

IDENTIFICATION
A.
Infrared Absorption
B. The retention time of the major peak of the Sample solution corresponds to that of a similar preparation of USP Triethyl Citrate RS, as obtained in the Assay.
ASSAY
To pass the test by Chromatography.
Acceptance criteria: ;99.0%–100.5% on the anhydrous basis
Specific Gravity: 1.135–1.139
Refractive Index: 1.439–1.441
Acidity:
Neutralized isopropyl alcohol: To a suitable quantity of isopropyl alcohol add 2–3 drops of bromothymol blue and just sufficient 0.10 N sodium hydroxide dropwise to produce a faint blue color. [Note— Prepare Neutralized isopropyl alcohol just prior to use.]
Sample solution: 32.0 g of Triethyl Citrate in 30 mL of Neutralized isopropyl alcohol
Analysis: Add bromothymol blue. Titrate with 0.10 N sodium hydroxide to a faint blue endpoint.
Acceptance criteria: NMT 1.0 mL of 0.10 N sodium hydroxide is required.
Water Determination: NMT 0.25%
Packaging and Storage: Preserve in tight containers.


Specifications of Triethyl Citrate BP Ph Eur Grade:
C12H20O7 --- 276.3 --- 77-93-0
Action and use: Excipient.

DEFINITION
Triethyl 2-hydroxypropane-1,2,3-tricarboxylate.
Content: 98.5 per cent to 101.0 per cent (anhydrous substance).

CHARACTERS
Appearance: Clear, viscous, colourless or almost colourless, hygroscopic liquid.
Solubility: Soluble in water, miscible with ethanol (96 per cent), slightly soluble in fatty oils.

IDENTIFICATION
First identification: A, B
Second identification: A, C, D
A. Refractive index (see Tests).
B. Infrared absorption spectrophotometry.
Comparison Ph. Eur. reference spectrum of triethyl citrate.
C. It gives the reaction of esters.
D. To 0.5 mL add 5 mL of ethanol (96 per cent) and 4 mL of dilute sodium hydroxide solution. Boil under reflux for about 10 min. 2 mL of the solution gives the reaction of citrates.

TESTS
Appearance: The substance to be examined is clear and not more intensely coloured than reference solution
Acidity: Dilute 10 g with 10 mL of previously neutralised ethanol (96 per cent), add 0.5 mL of bromothymol blue solution. Not more than 0.3 mL of 0.1 M sodium hydroxide is required to change the colour of the indicator to blue.
Refractive index: 1.440 to 1.446.
Related substances: To pass the test by Gas chromatography.
Limits:
-any impurity: for each impurity, maximum 0.2 per cent;
-total: maximum 0.5 per cent;
-disregard limit: 0.04 per cent.
Water: Maximum 0.25 per cent, determined on 1.000 g.
Sulfated ash: Maximum 0.1 per cent, determined on 1.0 ;g.


Specifications of Triethyl Citrate FCC Food Grade:
Ethyl Citrate
C12H20O7 Formula weight 276.29
INS: 1519 CAS 77-93-0

DESCRIPTION
Triethyl Citrate occurs as a practically colorless, oily liquid. It is slightly soluble in water but is miscible with alcohol and with ether.
Function: Solvent.

REQUIREMENTS
Assay: Not less than 99.0% and not more than 100.5% of C12H20O7, calculated on the anhydrous basis.
Acidity: (as citric acid) Not more than 0.02%.
Lead: Not more than 2 mg/kg.
Refractive Index: Between 1.439 and 1.443 at 25C; or between 1.440 and 1.444 at 20C.
Specific Gravity: Between 1.135 and 1.139 at 25C.
Water: Not more than 0.25%.

The MSDS-SDS Hazard Statement of Triethyl Citrate:

Triethyl Citrate SDS, Safety Data Sheet
MSDS Sheet
27-Feb-22

1. PRODUCT DESCRIPTION

Product Name & Other Names: Triethyl Citrate.
CAS Number: 77-93-0
EINECS EC Number: 201-070-7
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Supplier: As per letterhead.

2. HAZARD IDENTIFICATION

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP)

Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
This substance is not classified as dangerous according to Directive 67/548/EEC.

Labeling as per GHS & Regulation EC 1272/2008 (CLP) & GHS

GHS Label Elements
None

Signal Words: None

Precautionary statements:
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P281: Use personal protective equipment as required.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Product Name & Other Names: Triethyl Citrate.
CAS Number: 77-93-0
EINECS EC Number: 201-070-7

4. FIRST AID MEASURES

Always get medical attention after the first aid is over.

Emergency and First Aid Procedures:
Eyes - Flush with water for at least 15 minutes, raising and lowering eyelids occasionally. Get medical attention if irritation persists.
Skin - Thoroughly wash exposed area for at least 15 minutes. Remove contaminated clothing. Launder contaminated clothing before reuse. Get medical attention if irritation persists.
Ingestion - If swallowed, if conscious, give plenty of water. Immediately call a physician. Never give anything by mouth to an unconscious person.
Inhalation - Remove to fresh air. Give oxygen if breathing is difficult; give artificial respiration if breathing has stopped. Get medical attention.

5. FIREFIGHTING PROCEDURES

Extinguisher Media: Use media suitable to extinguish surrounding fire. Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Flammable Limits in Air % by Volume: N/A
Special hazards arising from the substance or mixture: Fumes, Carbon oxides.
Extinguishing Media Not recommended: Avoid using solid water jet as it may scatter the fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At elevated temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used.

6. SPILL OR LEAK PROCEDURES

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Ensure adequate ventilation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Do not approach facing the wind.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment cleanup procedures and Storage: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g., sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep-up and remove to an approved disposal container.

7. SPECIAL PRECAUTIONS

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.).
Conditions for safe storage, including any incompatibilities: Store cold to warm conditions, dry and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Do not store with incompatible materials like strong oxidizing.

8. SPECIAL PROTECTION INFORMATION

Airborne Exposure Limits: None established. Ensure adequate ventilation. Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels low.
Respiratory Protection (Specify Type):
None needed under normal conditions of use with adequate ventilation. NIOSH approved equipment should be worn if PELs are exceeded.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full-face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. PHYSICAL DATA

Appearance and Odor: Clear colorless or almost colorless oily liquid.
Odor: Odorless.
Odor threshold: Not available.
pH: Not available.
Relative density: 1.14
Melting point/freezing point: -55C literature.
Initial boiling point and boiling range: 294C literature.
Flash point: 151C literature.
Auto-ignition temperature: No data found.
Decomposition temperature: No data found.
Upper/lower flammability or explosive limits: No data found.
Vapor pressure: No data found.
Vapor density: No data found.
Evaporation rate: No data found.
Flammability (solid, gas): No data found.
Partition coefficient: n-octanol/water: No data found.
Solubility(ies): Soluble in water, miscible with ethanol (96 per cent).
Viscosity: No data found.

10. REACTIVITY DATA

Stability: It is stable
Conditions to Avoid: Heat, humidity, Dust generation.
Incompatibility (Materials to Avoid): Strong oxidizing.
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, nitrogen oxides.
Hazardous Polymerization: Will not occur.

11. TOXICITY DATA

Acute toxicity:
LD50 Oral - Rat - 5.900 mg/kg.
LD50 Dermal - Rabbit - > 5.000 mg/kg.
Carcinogenicity: This product present at levels greater than or equal to 0.1% is identified as probable, possible, or confirmed human carcinogen by IARC, NTP, ACGIH & OSHA.
Mutagenic Effects: No data found.
Developmental Toxicity: No data found.
Reproductive Effects: No data found.

12. ECOLOGICAL DATA

Toxicity to fish: No information available.
Toxicity to daphnia and other aquatic invertebrates: Immobilization EC50 - Daphnia magna (Water flea) - > 100 mg/l& - 48 h.
Toxicity: Avoid release into the environment.
Persistence and Degradability: Soluble in water Persistence is unlikely based on information available.
Mobility: Will be mobile in the environment due to its water solubility.
Bioaccumulation/ Accumulation: No data found.
Results of PBT and vPvB assessment: No data found.

13. DISPOSAL INFORMATION

Waste Disposal Methods: Dispose in accordance with all applicable Federal, State and Local regulations.

14. TRANSPORT INFORMATION

Land Transport DOT USA, TDG Canada & ADR/RID Europe: Not dangerous goods.
Sea Transport IMDG/IMO: Not dangerous goods.
Air Transport ICAO/IATA: Not dangerous goods.

15. REGULATORY INFORMATION

USA:
SARA 311/312 Hazard Categories
: See section 2 for more information
California Proposition 65:
Chemicals known to cause cancer: Substance is not listed.
Chemicals known to cause reproductive toxicity for females: Substance is not listed.
Chemicals known to cause reproductive toxicity for males: Substance is not listed.
Chemicals known to cause developmental toxicity: Substance is not listed.

16. ADDITIONAL INFORMATION

DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources, and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules, or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a professionally trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

Muby Chem P Ltd

Triethyl Citrate Manufacturers, Suppliers, Exporters, Wholesalers:

King of Chemicals manufacturers

Muby Chem Private Limited
Plot No. 2900/46&47 + 2900/163to167, GIDC, Ankleshwar, Dist. Bharuch, India
India, USA, UAE
TEL: (Office) 91-22-23774610, 91-22-23723564

e-mail: info@kingofchemicals.com

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We and our associates manufacture pure chemicals surpassing Monograph Specifications of Analytical Reagent Standards, British & European Pharmacopoeia BP Ph Eur EP Standard, US Pharmacopoeia USP NF Standard, Indian Pharmacopoeia IP Standard, Japan Pharmacopoeia JP Standard, FCC Food Grade Standard.

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