Specifications, Uses, SDS of Sodium Citrate Manufacturers

	King of Chemicals
Specifications, Properties, Uses, SDS of Monosodium Disodium Trisodium Citrate, Sodium Citrate USP BP Ph Eur IP Reagent FCC Food Grade Manufacturer Supplier Exporter Wholesale & Small Packs, CAS Number 18996-35-5 for Monosodium citrate, 144-33-2 for Disodium citrate and 68-04-2 for Trisodium citrate anhydrous, 6132-04-3 for Trisodium citrate dihydrate.
King of Chemicals has several associated companies having accreditations like cGMP, GLP - FDA Approved Good Manufacturing Practice and Good Laboratory Practice of WHO standard, ISO-9001, ISO-14001, ISO/IEC 17025, ISO ISO-45000, HACCP, FSSC 220000, FSSAI, "REACH" Registered, Kosher & Halal Certified. DMF support can be made available if needed. We offer USP NF BP Ph Eur EP IP JP Analytical Reagent FCC Food Grade Chemicals & Nutraceuticals.

Muby Chem Pvt. Ltd. is a several decades old group of companies, engaged in manufacturing, supplying, distributing, wholesale supplies of Monosodium Disodium Trisodium Citrate, Sodium Citrate for actual users, including retail or small pack supplies for research and development work.

We supply fine and speciality chemicals, pharmaceutical excipients, mineral fortifiers in chemically pure, analytical reagent grade, IP BP USP Ph Eur EP JP and other pharmaceutical grade monograph including FCC Food grade chemicals and Nutraceuticals at best prices. We and/or our associated units have all the facilities to supply as per cGMP standard observing good manufacturing practice and good laboratory practice. We can assure low microbial count and also offer a test certificate for the same. We maintain warehouses across USA, India, and UAE. Our group exports to USA, Canada, Mexico, Argentina, Brazil, Chile, Korea, Malaysia, Thailand, Indonesia, Europe, and several other parts of the world. We supply in wholesale container loads to small pack of few grams. Solid products may be specified for it size and shape as desired by the buyer.

Monosodium citrate, Sodium Dihydrogen Citrate Manufacturer

Disodium citrate, Disodium hydrogen citrate Supplier

Trisodium citrate, Sodium citrate Manufacturer Exporter

Monosodium Disodium Trisodium Citrate, Sodium Citrate CAS Number 18996-35-5 for Monosodium citrate, 144-33-2 for Disodium citrate and 68-04-2 for Trisodium citrate anhydrous, 6132-04-3 for Trisodium citrate dihydrate

The Properties, Specifications, Monograph and Uses of Monosodium Disodium Trisodium Citrate, Sodium Citrate:

Monosodium Citrate or Sodium Dihydrogen Citrate: CAS Number: 18996-35-5, EINECS EC Number: 242-734-6, Molecular Formula: C6H7NaO7 or HOC(COONa)(CH2COOH)2, Molecular Weight: 214.1

Disodium hydrogen citrate or Sodium hydrogencitrate or Di-Sodium hydrogen citrate: CAS Number: 6132-05-4 for sesquihydrate and 144-33-2 for anhydrous, EINECS EC Number: 205-623-3, Molecular Formula: HOC(COOH)(CH2COONa)2-1.5H2O for sesquihydrate and HOC(COOH)(CH2COONa)2 for anhydrous, Molecular Weight: 263.11 for sesquihydrate and 236.08 for anhydrous

Trisodium Citrate or Sodium Citrate: CAS Number 68-04-2 for Trisodium citrate anhydrous, 6132-04-3 for Trisodium citrate dihydrate, Molecular Weight 258.07, Chemical Formula C6H5Na3O7

Trisodium citrate has the chemical formula of Na3C6H5O7. It is sometimes referred to simply as "sodium citrate", though sodium citrate can refer to any of the three i.e. Monosodium Disodium Trisodium Citrate. Sodium citrate is chiefly used as a food additive, usually for flavor or as a preservative. Its E number is E331. Sodium citrate is employed as a flavoring agent in certain varieties of club soda. It is common as an ingredient in bratwurst, and is also used in commercial ready-to-drink beverages and drink mixes, contributing a tart flavor. It is found in gelatin mix, ice cream, yogurt, jams, sweets, milk powder, processed cheeses, carbonated beverages, and wine. Sodium citrate can be used as an emulsifying stabilizer when making cheese. It is used today in blood-collection tubes and for the preservation of blood in blood banks. Sodium citrate is a particularly effective agent for removal of carbonate scale from boilers without removing them from operation and for cleaning automobile radiators.

Sodium acid citrate or Disodium hydrogen citrate or Disodium citrate is used as an antioxidant in food and to improve the effects of other antioxidants. It is used as acidity regulator in ready-to-drink beverage and drink mixes. It is also used as an emulsifying stabilizer when making cheese. It is used as an alkalinizing agent which neutralize extra acid in the urine and blood, provides relief from dehydration and metabolic acidosis, anticoagulant which precludes the blood from clotting.

Monosodium citrate, more correctly, sodium dihydrogen citrate is an acid salt of citric acid. It has a sour taste similar to citric acid, and is salty as well. It is often used as a food preservative, and as a flavoring in the food industry. In the pharmaceutical industry it is used to control pH. It may be used as an alkalizing agent, buffering agent, emulsifier, or as a strong sequestering agent.

According to the FDA Select Committee on Generally Recognized as Safe (GRAS) food substances, citrate salts, including sodium citrate, are generally regarded as safe when used in normal quantities.

Specifications of Monosodium Citrate or Sodium Dihydrogen Citrate:
CAS Number: 18996-35-5
Chemical Formula: C6H7NaO7
Molecular Weight: 214.1
Assay (on dry basis): 98% to 102%
Appearance: White, odorless crystalline powder.
Solubility: Freely soluble in water; practically insoluble in ethanol.
pH of 10% solution: 3 to 4
Chloride: 100 ppm maximum.
Sulfate: 200 ppm maximum.
Heavy metals: 10 ppm maximum.
Loss on drying: 5% maximum.

Sodium Acid Citrate BP Ph Eur Grade Specifications:
Disodium Hydrogen Citrate
C6H6Na2O7-1.5H2O --- 263.1 --- CAS 144-33-2
Action and use: Anticoagulant.

DEFINITION
Sodium Acid Citrate contains not less than 98.0% and not more than 104.0% of C6H6Na2O7-1.5H2O.

CHARACTERISTICS
A white powder.
Freely soluble in water; practically insoluble in ethanol (96%).

IDENTIFICATION
Yields the reactions characteristic of sodium salts and of citrates.

TESTS
Acidity: pH of a 3% w/v solution, 4.9 to 5.2
Arsenic: 0.50 g dissolved in 25 mL of water complies with the limit test for arsenic (2 ppm).
Chloride: Dissolve 1.0 g in 100 mL of water. 15 mL of the resulting solution complies with the limit test for chlorides, (330 ppm).
Oxalate: To pass the test. (150 ppm, calculated as anhydrous oxalic acid).
Sulfate: Dissolve 0.50 g in 57 mL of water and add 3 mL of 2M hydrochloric acid. 15 mL of the resulting solution complies with the limit test for sulfates, (0.12%).
Readily carbonisable substances: Heat 1.0 g, in powder, with 10 mL of sulfuric acid for 30 minutes in a water bath protected from light. Not more than a pale brown colour is produced.

Sodium Citrate USP Grade Specifications:
C6H5Na3O7 --- 258.07
1,2,3-Propanetricarboxylic acid, 2-hydroxy-, trisodium salt;
Trisodium citrate (anhydrous) CAS 68-04-2
C6H5Na3O7-2H2O --- 294.10
Trisodium citrate dihydrate --- CAS 6132-04-3

DEFINITION
Sodium Citrate is anhydrous or contains two molecules of water of hydration. It contains NLT 99.0% and NMT 100.5% of C6H5Na3O7, calculated on the anhydrous basis.

IDENTIFICATION
A. Identification Tests: General, Sodium
Sample solution: 50 mg/mL
Acceptance criteria: Meets the requirements
B. Identification Tests—General, Citrate
Sample solution: 50 mg/mL
Acceptance criteria: Meets the requirements
C. Upon ignition, it yields an alkaline residue that effervesces when treated with 3 N hydrochloric acid.

ASSAY
Procedure
Sample: Add 100 mL of glacial acetic acid to 350 mg of Sodium Citrate (previously dried at 180C for 18 h) in a 250-mL beaker. Stir until completely dissolved.
Analysis: Titrate with 0.1 N perchloric acid, determining the endpoint potentiometrically. Perform a blank determination and make any necessary correction. Each mL of 0.1 N perchloric acid is equivalent to 8.602 mg of C6H5Na3O7.
Acceptance criteria: 99.0% 100.5% on the anhydrous basis

Sodium Citrate FCC Food Grade
Trisodium Citrate
C6H5Na3O7 Formula wt, anhydrous 258.07
C6H5Na3O7-2H2O Formula wt, dihydrate 294.10
INS: 331(iii) CAS: anhydrous 68-04-2
CAS: dihydrate 6132-04-3

DESCRIPTION
Sodium Citrate occurs as colorless crystals or as a white, crystalline powder. It is anhydrous or contains two molecules of water of crystallization. One gram of the dihydrate dissolves in 1.5 mL of water at 25C and in 0.6 mL of boiling water. It is insoluble in alcohol.

REQUIREMENTS
Identification: A 1:20 aqueous solution gives positive tests for Sodium and for Citrate.
Assay: Not less than 99.0% and not more than 100.5% of C6H5Na3O7, calculated on the anhydrous basis.
Alkalinity: Passes test.
Lead: Not more than 2 mg/kg.
Water: Anhydrous: Not more than 1%; Dihydrate: Between 10.0% and 13.0%.

Monosodium Citrate or Sodium Dihydrogen Citrate SDS, Safety Data Sheet
MSDS, Material Safety Data Sheet 25-Jul-21

Product Name & Other Names: Monosodium Citrate or Sodium Dihydrogen Citrate.
CAS No.: 18996-35-5
EINECS: EC Number: 242-734-6
Molecular Weight: 214.1
Chemical Formula: C6H7NaO7 or HOC(COONa)(CH2COOH)2
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
This substance is not classified as dangerous according to Directive 67/548/EEC.

Precautionary statements:
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P281: Use personal protective equipment as required.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.

Product Name/Synonyms: Monosodium Citrate or Sodium Dihydrogen Citrate.
CAS No.: 18996-35-5
EINECS: EC Number: 242-734-6

Always seek medical attention after first aid measures are provided.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Note to Physician: To treat symptomatically.

Flammability of the Product: The product is not reported as combustible. It may ignite at high temperature.
Auto-Ignition Temperature: NA.
Products of Combustion: It emits toxic oxides of carbon and organic fumes when heated to decomposition. Related Sodium Compounds will form.
Explosion: Slightly explosive in presence of heat.
Fire Extinguishing Media: Water spray. Use means suitable for extinguishing surrounding fire. Water spray, dry chemical, alcohol foam, or carbon dioxide.
Extinguishing Media Not recommended: Avoid using solid water jet as it may scatter the fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

Personal precautions, protective equipment and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Ensure adequate ventilation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment cleanup procedures and Storage: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep-up and remove to an approved disposal container. Finish cleaning by spreading water on the contaminated surface and allow evacuating as per law.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat or smoke while handling. Avoid contact with skin, eyes and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Provide appropriate exhaust ventilation at places where dust is formed. If you feel unwell, seek medical attention. Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, reducing agents, bases and heat and combustible substances. Hygroscopic.

8. Exposure Controls/Personal Protection
Airborne Exposure Limits: This product does not contain any hazardous materials with occupational exposure limits established by the region-specific regulatory bodies.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: White, odorless crystalline powder.
Odor: None
Odor threshold: Not available.
pH: Not available.
Relative density: Not available.
Melting Point: 209C to 215C.
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Readily soluble in water
Viscosity: Not available.
Molecular Weight: 214.1
Chemical Formula: C6H7NaO7 or HOC(COONa)(CH2COOH)2

Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits toxic oxides of carbon along with organic fumes when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents, reducing agents, bases and heat.
Conditions to Avoid: Moisture, Heat, Incompatibles.

LD50 Intravenous Mouse: 49 mg/kg
LD50 Intraperitoneal Rat: 1.348 mg/kg
Carcinogenic Effects: Not a reported carcinogen by IARC, NTP, ACGIH and OSHA.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

Freshwater Fish LC50: = 1516 mg/L, 96h (Lepomis macrochirus)
Water Flea EC50: = 85 mg/L, 24h (Daphnia magna)
BOD5 and COD: Not available.
Environmental Fate: No information found. The product itself and its products of degradation are not toxic.
Persistence and degradability: Expected to be biodegradable
Bioaccumulative potential: No information available but Persistence is unlikely due to Solubility in water.
Mobility in soil: No information available but expected to be mobile.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. Small amounts of this material may be suitable for sanitary sewer or trash disposal.

Land Transport DOT USA, TDG Canada & ADR/RID Europe: Not Regulated.
Sea Transport IMDG/IMO: Not Regulated.
Air Transport IATA/ICAO: Not Regulated.

USA:
SARA 311/312 Hazards: None.
California Prop 65: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

Disodium hydrogen citrate sesquihydrate or Sodium hydrogencitrate sesquihydrate SDS, Safety Data Sheet
MSDS, Material Safety Data Sheet 25-Jul-21

Product Name & Other Names: Disodium hydrogen citrate sesquihydrate or Sodium hydrogencitrate sesquihydrate or Di-Sodium hydrogen citrate sesquihydrate.
CAS No.: 6132-05-4 for sesquihydrate and 144-33-2 for anhydrous
EINECS: EC Number: 205-623-3
Molecular Weight: 263.11 for sesquihydrate and 236.08 for anhydrous
Chemical Formula: HOC(COOH)(CH2COONa)2-1.5H2O for sesquihydrate and HOC(COOH)(CH2COONa)2 for anhydrous
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
This substance is not classified as dangerous according to Directive 67/548/EEC.

Precautionary statements:
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P281: Use personal protective equipment as required.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Note to Physician: To treat symptomatically.

Flammability of the Product: The product is not reported as combustible. It may ignite at high temperature.
Auto-Ignition Temperature: NA.
Products of Combustion: It emits toxic oxides of carbon and organic fumes when heated to decomposition. Sodium Compounds will form.
Fire Extinguishing Media: Water spray. Use means suitable for extinguishing surrounding fire. Water spray, dry chemical, alcohol foam, or carbon dioxide.
Extinguishing Media Not recommended: Avoid using solid water jet as it may scatter the fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

Airborne Exposure Limits: This product does not contain any hazardous materials with occupational exposure limits established by the region-specific regulatory bodies.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: White crystalline powder.
Odor: None
Odor threshold: Not available.
pH: Between 4,9 and 5,2 (1 % aqueous solution).
Relative density: Not available.
Melting Point: 149C.
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Soluble in water
Viscosity: Not available.
Molecular Weight: 263.11 for sesquihydrate and 236.08 for anhydrous
Chemical Formula: HOC(COOH)(CH2COONa)2-1.5H2O for sesquihydrate and HOC(COOH)(CH2COONa)2 for anhydrous.

Acute Toxicity to Animals: Not available.
Carcinogenic Effects: Not a reported carcinogen by IARC, NTP, ACGIH and OSHA.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

Toxicity to Fish: Not available.
BOD5 and COD: Not available.
Persistence and degradability: Expected to be biodegradable
Bioaccumulative potential: Persistence is unlikely due to Solubility in water.
Mobility in soil: No information available but expected to be mobile.

Land Transport DOT USA, ADR/RID Europe & TDG Canada: Not Regulated.
Sea Transport IMDG/IMO: Not Regulated.
Air Transport IATA/ICAO: Not Regulated.

USA:
SARA 311/312 Hazards: None. See section 2.
California Prop 65: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

Sodium Citrate or Trisodium Citrate SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 25-Jul-21

Product Name & Other Names: Sodium Citrate or Citnatin or Citreme or Citrosoedine or Citrosodna or Natrocitral or Trisodium citrate dihydrate or 1,2,3-Propanetricarboxylic acid, 2-hydroxy-trisodium salt dihydrate or Citric acid trisodium salt dihydrate.
CAS No.: anhydrous 68-04-2; CAS: dihydrate 6132-04-3
EINECS: EC Number: 200-675-3
Molecular Weight: anhydrous 258.07; dihydrate 294.10
Chemical Formula: C6H5Na3O7 anhydrous 258.07; C6H5Na3O7-2H2O dihydrate 294.10
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
This substance is not classified as dangerous according to Directive 67/548/EEC.

Precautionary statements:
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P281: Use personal protective equipment as required.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+313: If eye irritation persists get medical advice/attention.

Flammability of the Product: The product is not reported as combustible. It may ignite at high temperature.
Products of Combustion: It emits toxic oxides of carbon and organic fumes when heated to decomposition.
Explosion: Slightly explosive in presence of heat.
Fire Extinguishing Media: Water spray. Use means suitable for extinguishing surrounding fire. Water spray, dry chemical, alcohol foam, or carbon dioxide.
Extinguishing Media Not recommended: Avoid using solid water jet as it may scatter the fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment cleanup procedures and Storage: Do not inhale vapors, mist, or gas. Avoid dust formation. Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g., sand, earth, diatomaceous earth, vermiculite). Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents.

Exposure Limits: This product does not contain any hazardous materials with occupational exposure limits established by the region-specific regulatory bodies.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full-face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: White crystals or powder or granules.
Odor: None
Odor threshold: Not available.
pH: 7.5-9 at 1% solution at 25 C (77F)
Relative density: around 1.7
Melting point/freezing point: Not available.
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Readily soluble in water
Viscosity: Not available.
Molecular Weight: anhydrous 258.07; dihydrate 294.10
Molecular Formula: C6H5Na3O7 anhydrous 258.07; C6H5Na3O7-2H2O dihydrate 294.10

Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: It emits toxic oxides of carbon along with organic fumes when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Strong oxidizing agents and heat.
Conditions to Avoid: Moisture, Heat, Incompatibles.

Toxicity to Animals: LD50 oral rat 6730 mg/kg.
Carcinogenicity: Not as human carcinogen by IARC, ACGIH, OSHA and NTP.
Teratogenic Effects: Not available.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.

EC50: 96h 18000 - 32000 mg/L (Chlorella vulgaris, Fresh Water Algae) for CAS No.: 68-04-2
LC50: 96h 18000-32000mg/L (Poecilia reticulata Fish) for CAS No.: 68-04-2
Persistence and Degradability: No information available.
Mobility: No information available.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state, and local requirements. Small amounts of this material may be suitable for sanitary sewer or trash disposal.

Land Transport DOT USA, TDG Canada & ADR/RID Europe: Not Regulated.
Sea Transport IMDG/IMO: Not Regulated.
Air Transport IATA/ICAO: Not Regulated.

USA:
SARA 311/312 Hazards: None.
California Prop 65:
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

Monosodium Disodium Trisodium Citrate, Sodium Citrate Manufacturers, Suppliers, Exporters, Wholesalers:

Plot No. 2900/46&47 + 2900/163to167, GIDC, Ankleshwar, Dist. Bharuch, India
India, USA, UAE
TEL: (Office) 91-22-23774610, 91-22-23723564

If I give you “My Word” Nobody can undo it.
If I sign an “Agreement” my Lawyer will undo it

Our products are for industrial and laboratory use only. The user must test the material before use. We are not dispensing chemists or druggist and do not offer over the counter type (OTC) products for medical use by individuals.