Specifications, Uses, SDS of Calamine USP BP Ph Eur IP Manufacturers

	King of Chemicals Manufacturers
Specifications, Properties, Uses, SDS of Calamine USP BP Ph Eur IP Grade Manufacturer Supplier Exporter Wholesale & Small Packs, CAS Number 8011-96-9.
King of Chemicals has several associated companies having accreditations like cGMP, GLP - FDA Approved Good Manufacturing Practice and Good Laboratory Practice of WHO standard, ISO-9001, ISO-14001, ISO/IEC 17025, ISO ISO-45000, HACCP, FSSC 220000, FSSAI, "REACH" Registered, Kosher & Halal Certified. e-CTD and DMF support can be made available if needed. We offer USP NF BP Ph Eur EP IP JP Analytical Reagent FCC Food Grade Chemicals & Nutraceuticals.

Muby Chem Pvt. Ltd. is a several decades old group of companies, engaged in manufacturing, supplying, distributing, wholesale supplies of Calamine USP BP Ph Eur IP Grade for actual users, including retail or small pack supplies for research and development work.

We supply fine and speciality chemicals, pharmaceutical excipients, mineral fortifiers in chemically pure, analytical reagent grade, IP BP USP Ph Eur EP JP and other pharmaceutical grade monograph including FCC Food grade chemicals and Nutraceuticals at best prices. We and/or our associated units have all the facilities to supply as per cGMP standard observing good manufacturing practice and good laboratory practice. We can assure low microbial count and also offer a test certificate for the same. We maintain warehouses across USA, India, and UAE. Our group exports to USA, Canada, Mexico, Argentina, Brazil, Chile, Korea, Malaysia, Thailand, Indonesia, Europe, and several other parts of the world. We supply in wholesale container loads to small pack of few grams. Solid products may be specified for it size and shape as desired by the buyer.

Calamine USP Grade Specifications:
Iron oxide (Fe2O3), mixture with zinc oxide;
Calamine (pharmaceutical preparation)) CAS 8011-96-9

DEFINITION
Calamine is Zinc Oxide with a small proportion of ferric oxide, and contains, after ignition, NLT 98.0% and NMT 100.5% of zinc oxide (ZnO).

IDENTIFICATION
A. Identification Tests—General, Zinc
B.
Sample: 1 g
Analysis: Add 10 mL of 3 N hydrochloric acid to the Sample, heat to boil, and filter.
Acceptance criteria: The filtrate assumes a reddish color upon the addition of ammonium thiocyanate.

DEFINITION
Calamine is a basic zinc carbonate suitably coloured with iron(III) oxide.

CHARACTERISTICS
An amorphous, impalpable, pink or reddish brown powder, the colour depending on the variety and amount of iron(III) oxide present and the process by which it is incorporated. Practically insoluble in water. It dissolves with effervescence in hydrochloric acid .

IDENTIFICATION
A. Yields the reactions characteristic of carbonates.
B. To 2 g add 5 ml of hydrochloric acid and heat to boiling; if necessary, add hydrochloric acid drop wise until a bright yellow solution is obtained. Cool and add 13.5 M ammonia until the first sign of precipitate (solution A). The solution yields characteristic of iron salts. Dilute 1 ml of solution A to 5 ml with water; the solution yields the reaction characteristic of zinc salts.

TESTS
Calcium: Dissolve 0.50 g in a mixture of 10 ml of water and 2.5 ml of glacial acetic acid and filter. To 0.5 ml of the filtrate add 15 ml of 5 M ammonia and 2 ml of a 2.5% w/v solution of ammonium oxalate and allow to stand for 2 minutes. The solution remains clear.
Soluble barium salts: To the remainder of the filtrate obtained in the test for Calcium add 2 ml of 1 M sulphuric acid and allow to stand for 5 minutes. The solution remains clear.
Lead: Not more than 150 ppm when determined by atomic absorption spectrophotometry,
Chloride: Dissolve 0.15 g in water with the addition of 1 ml of nitric acid, filter and dilute to 30 ml with water. The resulting solution complies with the limit test for chlorides (0.07%).
Sulphate: Dissolve 0.1 g in water with the addition of 3 ml of 2 M hydrochloric acid, filter and dilute to 60 ml with water. The resulting solution complies with the limit test for sulphates, (0.6%).
Ethanol-soluble dyes: Shake 1.0 g with 10 ml of ethanol (90%) and filter. The filtrate is colourless,.
Matter insoluble in hydrochloric acid: Dissolve 1 g in 20 ml of warm 2 M hydrochloric acid and filter. The residue, when washed with water and dried to constant weight at 105C, weighs not more than 10 mg.
Water-soluble dyes: Shake 1.0 g with 10 ml of water and filter. The filtrate is colourless.
Residue on ignition: 68.0 to 74.0%, when ignited at a temperature not lower than 900C until, after further ignition, two successive weighing do not differ by more than 0.2% of the weight of the residue. Use 1 g.

Calamine SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 22-March-25

Product Name & Other Names: Calamine
CAS Number: Mixture also called 8011-96-9
Relevant uses and uses advised against (if any): Industrial Manufacturing.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Hazard statements:
H410: Very toxic to aquatic life with long lasting effects

Precautionary statements:
P273: Avoid release to the environment.
P391: Collect spillage.
P501: Dispose of contents/container in accordance with local/regional/national/international regulation.

Ingredient 1: Zinc Oxide
CAS Number: 1314-13-2
EINECS EC-No.: 215-222-5
% by Weight: >90%
Ingredient 2: Diiron trioxide
CAS Number: 1309-37-1
EINECS EC-No.: 215-222-5
% by Weight: < 5%

Eye Contact: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin Contact: After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin with running water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases, and groin. Cover the irritated skin with an emollient. If irritation persists, seek medical attention.
Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.
If swallowed: Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

Flammability of the Product: Non-flammable.
Auto-Ignition Temperature: Not applicable.
Products of Combustion: Zinc Iron & their oxide.
Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes.

Personal precautions, protective equipment, and emergency procedures: Ventilate area of leak or spill. Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep-up and remove to an approved disposal container.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.).
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents and acids.

Occupational Exposure Limits for Zinc Oxide:
USA ACGIH, ACGIH TWA (mg/m³): 2 mg/m³
USA ACGIH, ACGIH STEL (mg/m³): 10 mg/m³
USA OSHA, OSHA PEL (TWA) (mg/m³): 5 mg/m³
USA NIOSH, NIOSH REL (TWA) (mg/m³): 5 mg/m³
Occupational Exposure Limits for Diiron trioxide:
USA. ACGIH Threshold Limit Values (TLV) (mg/m3) (TWA) 5

Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels low.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice.

Appearance: Pink-yellowish powdered solid.
Odor: Odorless.
Odor threshold: No information found.
pH: No data found.
Relative density: around 5.6
Melting point/freezing point: No information found.
Initial boiling point and boiling range: No information found.
Flash point: No information found.
Auto-ignition temperature: No information found.
Decomposition temperature: No information found.
Upper/lower flammability or explosive limits: No information found.
Vapor pressure: No information found.
Vapor density: No information found.
Evaporation rate: No information found.
Flammability (solid, gas): No information found.
Partition coefficient: n-octanol/water: No information found.
Solubility: Very slightly soluble in cold water, hot water.
Viscosity: No information found.

Stability: It is stable.
Incompatibility with various substances: Strong oxidizing agents & acids.
Polymerization: None reported.

LD50 Oral: No information found.
LC50: No information found.
Carcinogenicity: Not listed as a suspected/confirmed carcinogen by ACGIH, IARC, NTP, SHA.
Mutagenic Effects: No information found.
Teratogenic Effects: No information found.
Developmental Toxicity: No information found.
Reproductive Effects: No information found.

Toxicity to fish: LC50 - No information found.
Toxicity of the Products of Biodegradation: Insoluble in water. (can be separated from aqueous systems by sedimentation and/or filtration techniques). An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. Very toxic to aquatic life.
Persistence and Degradability: Likely to persist.
Mobility: Predicted to have low mobility in soil.
Bioaccumulation/ Accumulation: No information found.
Results of PBT and vPvB assessment: No information found.

Land Transport
DOT USA: Not a DOT regulated.
ADR/RID Europe:
UN3077: ENVIRONMENTALLY HAZARDOUS SUBSTANCE SOLID N.O.S. (Zinc Oxide)
Transport hazard Classes: 9
Packing group: III
Environmental hazards: Yes
Sea Transport IMDG/IMO:
UN3077: ENVIRONMENTALLY HAZARDOUS SUBSTANCE SOLID N.O.S. (Zinc Oxide)
Transport hazard Classes: 9
Packing group: III
Environmental hazards: Yes
Air Transport IATA/ICAO:
UN3077: ENVIRONMENTALLY HAZARDOUS SUBSTANCE SOLID N.O.S. (Zinc Oxide)
Transport hazard Classes: 9
Packing group: III
Environmental hazards: Yes.

USA:
SARA 311/312 Hazards: Aquatic Hazard..
California Prop. 65: Not listed.

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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Calamine Manufacturers, Suppliers, Exporters, Wholesalers:

Plot No. 2900/46&47 + 2900/163to167, GIDC, Ankleshwar, Dist. Bharuch, India
India, USA, UAE
TEL: (Office) 91-22-23774610, 91-22-23723564

If I give you “My Word” Nobody can undo it.
If I sign an “Agreement” my Lawyer will undo it

Our products are for industrial and laboratory use only. The user must test the material before use. We are not dispensing chemists or druggist and do not offer over the counter type (OTC) products for medical use by individuals.

Specifications, Properties, Uses, SDS of Calamine USP BP Ph Eur IP Grade Manufacturer Supplier Exporter Wholesale & Small Packs, CAS Number 8011-96-9.

Calamine Manufacturers, Suppliers, Exporters, Wholesalers: