Specifications, Uses, SDS of Heavy Bismuth Subnitrate Manufacturers

	King of Chemicals
Specifications, Properties, Uses, SDS of Heavy Bismuth Subnitrate USP BP Ph Eur Grade Manufacturer Supplier Exporter Wholesale & Small Packs, CAS Number 1304-85-4.
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Muby Chem Pvt. Ltd. is a several decades old group of companies, engaged in manufacturing, supplying, distributing, wholesale supplies of Heavy Bismuth Subnitrate for actual users, including retail or small pack supplies for research and development work.

We supply fine and speciality chemicals, pharmaceutical excipients, mineral fortifiers in chemically pure, analytical reagent grade, IP BP USP Ph Eur EP JP and other pharmaceutical grade monograph including FCC Food grade chemicals and Nutraceuticals at best prices. We and/or our associated units have all the facilities to supply as per cGMP standard observing good manufacturing practice and good laboratory practice. We can assure low microbial count and also offer a test certificate for the same. We maintain warehouses across USA, India, and UAE. Our group exports to USA, Canada, Mexico, Argentina, Brazil, Chile, Korea, Malaysia, Thailand, Indonesia, Europe, and several other parts of the world. We supply in wholesale container loads to small pack of few grams. Solid products may be specified for it size and shape as desired by the buyer.

CAS Number: 1304-85-4, EINECS EC Number: 215-136-8, Molecular Formula: Bi5O(OH)9(NO3)4 , Molecular Weight: 1461.99, HS Code 28342990

Bismuth subnitrate is an inorganic salt of bismuth. Bismuth is a non-essential trace element with an estimated normal daily intake in humans between 5 and 20 µg. Bismuth subnitrate, also referred to as bismuth oxynitrate or bismuthyl nitrate, is a highly water-soluble crystalline compound that has been used as a treatment for duodenal ulcers and anti-diarrheic agent. The use of bismuth substrate as an active ingredient in over-the-counter antacids is approved by the FDA. The synonyms of the product are Bismuthyl nitrate, Bismuth(III) nitrate basic, Bismuth(III) oxynitrate, Bismuth(III) subnitrate.

Bismuth Subnitrate USP Grade Specifications
Bi5O(OH)9(NO3)4 1461.99
Bismuth hydroxide nitrate oxide Bi5O(OH)9(NO3)4 --- CAS 1304-85-4.

Bismuth Subnitrate is a basic salt that contains the equivalent of not less than 79.0 percent of bismuth trioxide (Bi2O3), calculated on the dried basis.

Identification: It responds to the tests for Bismuth and for Nitrate.
Loss on drying: Dry it at 105 for 2 hours: it loses not more than 3.0% of its weight.
Carbonate: Add 3 g to 3 mL of warm nitric acid: no effervescence occurs. Pour the solution into 100 mL of water: a white precipitate forms. Filter, evaporate the filtrate on a steam bath to 30 mL, again filter the liquid, divide the latter filtrate into portions of 5 mL each, and use these several portions in the tests for Chloride, Sulfate, Copper, Lead, and Silver.
Chloride: A 10-mL portion of the test liquid retained in the test for Carbonate shows no more chloride than corresponds to 0.50 mL of 0.020 N hydrochloric acid (0.035%).
Sulfate: To a 5-mL portion of the test liquid retained in the test for Carbonate add 5 drops of barium nitrate: no turbidity is produced immediately.
Limit of ammonium salts: Boil about 100 mg with 5 mL of 1 N sodium hydroxide: the vapor does not turn moistened red litmus paper blue.
Arsenic, Method: Mix 375 mg with 5 mL of water, cautiously add 2 mL of sulfuric acid, and heat the mixture until fumes of sulfur trioxide are copiously evolved. Cool, cautiously add 10 mL of water, and again evaporate to strong fuming, repeating, if necessary, to remove any trace of nitric acid. The limit is 8 ppm.
Copper: To a 5-mL portion of the test liquid retained in the test for Carbonate add a slight excess of 6 N ammonium hydroxide: the liquid does not exhibit a bluish color.
Lead: Mix a 5-mL portion of the test liquid retained in the test for Carbonate with an equal volume of 2 N sulfuric acid: the liquid does not become cloudy.
Silver: To a 5-mL portion of the test liquid retained in the test for Carbonate add hydrochloric acid, dropwise: no precipitate is formed that is insoluble in a slight excess of hydrochloric acid, but that is soluble in 6 N ammonium hydroxide.
Limit of alkalies and alkaline earths: Boil 1.0 g with 20 mL of a mixture of equal volumes of 6 N acetic acid and water, cool, and filter. Add 2 mL of 3 N hydrochloric acid, precipitate the bismuth by the addition of hydrogen sulfide, boil the mixture, and filter it. Add 5 drops of sulfuric acid to the filtrate, evaporate to dryness, and ignite to constant weight: the weight of the residue does not exceed 5 mg (0.5%).

Heavy Bismuth Subnitrate BP Ph Eur Grade Specifications
4[BiNO3(OH)2],BiO(OH) -- 1462 -- CASc1304-85-4

DEFINITION
Content: 71.0 per cent to 74.0 per cent of Bi (Ar 209.0) (dried substance).

CHARACTERS
Appearance: White or almost white powder.
Solubility: Practically insoluble in water and in ethanol (96 per cent). It dissolves in mineral acids with decomposition.

IDENTIFICATION
A. Dilute 1 ml of solution S1 (see Tests) to 5 ml with water and add 0.3 ml of potassium iodide solution. A black precipitate is formed which dissolves into an orange solution with the addition of 2 ml of potassium iodide solution.
B. It gives reaction (b) of bismuth.
C. It gives the reaction of nitrates.
D. pH: maximum 2.0 for solution S2 (see Tests).

TESTS
Solution S1: Shake 5.0 g by gently heating in 10 ml of water and add 20 ml of nitric acid. Heat until dissolution, cool and dilute to 100 ml with water.
Solution S2: Place 1.00 g in a 20 ml volumetric flask and add 2.0 ml of lead-free nitric acid. Allow acid attack to take place without heating and if necessary warm slightly at the end to completely dissolve the test sample. Add 10 ml of water, shake and add, in small fractions, 4.5 ml of lead-free ammonia; shake and allow to cool. Dilute to 20.0 ml with water, shake again is required to change the colour of the indicator to pink.
Chlorides: Maximum 200 ppm.
Copper: Maximum 50.0 ppm.
Lead: Maximum 20.0 ppm.
Silver: Maximum 25.0 ppm.
Substances not precipitated by ammonia: Maximum 1.0 per cent.
To 20 ml of solution S1, add concentrated ammonia until an alkaline reaction is produced and filter. Wash the residue with water and evaporate the combined filtrate and washings to dryness on a water-bath. To the residue, add 0.3 ml of dilute sulphuric acid R and ignite.
The residue weighs a maximum of 10 mg.
Loss on drying: Maximum 3.0 per cent, determined on 1.000 g by drying in an oven at 105C.

Heavy Bismuth Subnitrate or Bismuth Nitrate SDS, Safety Data Sheet
MSDS, Material Safety Data Sheet 15-Jul-21

Product Name & Other Names: Heavy bismuth subnitrate or Bismuth (III) nitrate basic or Bismuthyl nitrate or Bismuth(III) oxynitrate or Bismuth(III) subnitrate.
CAS No.: 1304-85-4
EINECS EC Number: 215-136-8
Molecular Weight: 1461.99
Chemical Formula: Bi5O(OH)9(NO3)4
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Oxidizing solids Category 3, H272
Skin corrosion/irritation Category 2, H315
Serious eye damage/eye irritation Category 2A, H319
Specific target organ toxicity - single exposure Category 3, Respiratory system, H335
Hazardous to the aquatic environment, acute hazard Category 3, H402

Hazard Statements:
H272: May intensify fire; oxidizer.
H315 : Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H402: Harmful to aquatic life.

Precautionary Statements
P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P220: Keep/Store away from clothing/other combustible materials.
P221: Take any precaution to avoid mixing with combustibles.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash ... thoroughly after handling.
P273: Avoid release to the environment.
P280-Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P314: Get Medical advice/attention if you feel unwell.
P360: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P332+P313: If skin irritation occurs: Get medical advice/attention.
P337+313: If eye irritation persists get medical advice/attention.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P370+378: In case of fire: Use Dry chemical, carbon dioxide, Halon, water spray, or fog for extinction. If water is used, apply from as far a distance as possible.
P362: Take off contaminated clothing and wash before reuse.
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.

Inhalation: If inhaled, remove to fresh air. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention.

Fire: Not combustible, but substance is a strong oxidizer and its heat of reaction with reducing agents or combustibles may cause ignition.
Explosion: Some nitrates may explode when shocked, exposed to heat or flame, or by spontaneous chemical reaction. Sealed containers may rupture when heated. Sensitive to mechanical impact.
Fire Extinguishing Media: Dry chemical, carbon dioxide, Halon, water spray, or fog. If water is used, apply from as far a distance as possible. Water spray may be used to keep fire exposed containers cool. Do not allow water runoff to enter sewers or waterways.
Extinguishing Media Not recommended: None specified.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

Personal precautions, protective equipment, and emergency procedures: Ventilate area of leak or spill. Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment cleanup procedures and Storage: Oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance damp using water spray. Do not touch spilled material. Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist, or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g., sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep-up and remove to an approved disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law.

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong reducing agents, alkaline bicarbonates, soluble iodides, gallic acid, calomel, tannins, salicylic acid. Isolate from any source of heat or ignition. Avoid storage on wood floors. Separate from incompatibles, combustibles, organic or other readily oxidizable materials. Keep away from sources of ignition - No smoking.

Airborne Exposure Limits: None established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

Appearance: Solid.
Odor: Odorless.
Odor threshold: Not available.
pH: Not available.
Relative density: around 4.93
Melting point/freezing point: Not available.
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor Pressure (mm Hg): Negligible @ 20C.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Insoluble in water
Viscosity: Not available.
Molecular Weight: 1461.99
Chemical Formula: Bi5O(OH)9(NO3)4

Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Oxides of bismuth and nitrogen and toxic metal fumes may form when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Alkaline bicarbonates, soluble iodides, gallic acid, calomel, tannins, salicylic acid.
Conditions to Avoid: Heat, flames, ignition sources and incompatibles.

Toxicity to Animals: Not available.
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as possible or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.

Toxicity data: Not available.
Persistence and Degradability: No information available.
Mobility: No information available.
Bioaccumulation/ Accumulation: No information available.
Results of PBT and vPvB assessment: No data available for assessment.

Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste facility. Processing use or contamination of this product may change the waste management options. Dispose of container and unused contents in accordance legal requirements.

Land Transport DOT USA, TDG Canada & ADR/RID Europe
Proper Shipping Name: Nitrates, inorganic, n.o.s.
Hazard Class: 5.1
UN/NA: UN1477
Packing Group: II
Sea Transport IMDG/IMO
Proper Shipping Name: Nitrates, inorganic, n.o.s.
Hazard Class: 5.1
UN/NA: UN1477
Packing Group: II
Air Transport IATA/ICAO
Proper Shipping Name: Nitrates, inorganic, n.o.s.
Hazard Class: 5.1
UN/NA: UN1477
Packing Group: II.

USA:
SARA 311/312: See section 2.
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

Heavy Bismuth Subnitrate Manufacturers, Suppliers, Exporters, Wholesalers:

Plot No. 2900/46&47 + 2900/163to167, GIDC, Ankleshwar, Dist. Bharuch, India
India, USA, UAE
TEL: (Office) 91-22-23774610, 91-22-23723564

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Our products are for industrial and laboratory use only. The user must test the material before use. We are not dispensing chemists or druggist and do not offer over the counter type (OTC) products for medical use by individuals. Check.

Specifications, Properties, Uses, SDS of Heavy Bismuth Subnitrate USP BP Ph Eur Grade Manufacturer Supplier Exporter Wholesale & Small Packs, CAS Number 1304-85-4.

Heavy Bismuth Subnitrate Manufacturers, Suppliers, Exporters, Wholesalers: