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Specifications, Properties, Uses, SDS of Bismuth Subgallate BP Ph Eur USP Grade Manufacturer Supplier Exporter Wholesale & Small Packs, CAS Number 99-26-3 or 149-91-7.

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Muby Chem Pvt. Ltd. is a several decades old group of companies, engaged in manufacturing, supplying, distributing, wholesale supplies of Bismuth Subgallate for actual users, including retail or small pack supplies for research and development work.

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Bismuth Subgallate Manufacturer Supplier Exporter
Bismuth Subgallate CAS Number 99-26-3 or 149-91-7

For Properties Specifications Uses of Bismuth Subgallate Click Properties, Specifications, Uses, Price, Process of Bismuth Subgallate Manufacturer.

For For SDS MSDS Sheet of Bismuth Subgallate Click SDS Safety Data Sheet MSDS Sheet of Bismuth Subgallate Manufacturer.

The Properties, Specifications, Monograph and Uses of Bismuth Subgallate:

CAS Number: 99-26-3 or 149-91-7, EINECS EC Number: 202-742-2, Molecular Formula: C7H5BiO6, Molecular Weight: 394.09, HS Code 2918 2990

Bismuth subgallate is a yellow colored substance that presents as an odorless powder that undergoes discoloration when exposed to sunlight. It is a heavy metal salt of gallic acid that is highly insoluble and poorly absorbed. Bismuth subgallate is most commonly available as an active ingredient in over-the-counter internal deodorant where it is often employed as the primary active ingredient. Bismuth subgallate is commonly used to treat malodor by deodorizing flatulence and stools.

Specifications of Bismuth Subgallate USP Grade
C7H5BiO6 -- 394.09
Gallic acid bismuth basic salt CAS 99-26-3.

Bismuth Subgallate is a basic salt which, when dried at 105 for 3 hours, contains the equivalent of not less than 52.0 percent and not more than 57.0 percent of Bi2O3.

Identification:
A: When heated to redness, it at first chars, leaving finally a yellow residue. This residue responds to the tests for Bismuth.
B: Agitate thoroughly about 100 mg with an excess of hydrogen sulfide, filter, and boil the filtrate to expel the dissolved gas. Cool, and add 1 drop of ferric chloride: a purplish blue mixture is produced.
Loss on drying: Dry it at 105 for 3 hours. It loses not more than 7.0% of its weight.
Limit of nitrate: Mix about 100 mg with 5 mL of 2 N sulfuric acid and 5 mL of ferrous sulfate, filter the mixture, and carefully superimpose the filtrate, without mixing, on 5 mL of sulfuric acid, in a test tube: no reddish brown color appears at the zone of contact of the two liquids.
Arsenic: Triturate 400 mg with an equal weight of calcium hydroxide, and ignite. Dissolve the residue in 5 mL of 3 N hydrochloric acid: the solution without further treatment meets the requirements of the test for Arsenic 211 (7.5 ppm).
Copper, Lead, and Silver: To pass the test.
Limit of alkalies and alkaline earths: Boil 1.0 g with 20 mL of a mixture of equal volumes of 6 N acetic acid and water, cool, and filter. Precipitate the bismuth from the filtrate by the addition of hydrogen sulfide, boil the mixture, and filter. Add 5 drops of sulfuric acid to the filtrate, evaporate to dryness, and ignite to constant weight: the weight of the residue does not exceed 5 mg (0.5%).
Free gallic acid: Shake 1.0 g with 20 mL of alcohol for 1 minute, filter and evaporate the filtrate to dryness on a steam bath, and dry the residue at 105 for 1 hour: the weight of the residue does not exceed 5 mg (0.5%).


Specifications of Bismuth Subgallate BP Ph Eur Grade
C7H5BiO6
394.1 --CAS 149-91-7
Ph Eur

DEFINITION
Complex of bismuth and gallic acid.
Content: 48.0 per cent to 51.0 per cent of Bi (Ar 209.0) (dried substance).

CHARACTERS
Appearance: Yellow powder.
Solubility: Practically insoluble in water and in alcohol. It dissolves in mineral acids with decomposition and in solutions of alkali hydroxides, producing a reddish-brown liquid.

IDENTIFICATION
A. Mix 0.1 g with 5 ml of water R and 0.1 ml of phosphoric acid R. Heat to boiling and maintain boiling for 2 min. Cool and filter. To the filtrate, add 1.5 ml of ferric chloride solution, a blackish-blue colour develops.
B. It gives reaction (b) of bismuth (2.3.1).

TESTS
Solution S: In a porcelain or quartz dish, ignite 1.0 g, increasing the temperature very gradually. Heat in a muffle furnace at 600 ± 50C for 2 h. Cool and dissolve the residue with warming in 4 ml of a mixture of equal volumes of lead-free nitric acid and water and dilute to 20 ml with water.
Acidity: Shake 1.0 g with 20 ml of water R for 1 min and filter. To the filtrate add 0.1 ml of methyl red solution. Not more than 0.15 ml of 0.1 M sodium hydroxide is required to change the colour of the indicator to yellow.
Chlorides: Maximum 200 ppm.
Nitrates: Maximum 0.2 per cent.
Copper: Maximum 50.0 ppm.
Lead: Maximum 20.0 ppm.
Silver: Maximum 25.0 ppm.
Substances not precipitated by ammonia: Maximum 1.0 per cent.
Loss on drying: Maximum 7.0 per cent, determined on 1.000 g by drying in an oven at 105C for 3 h.


The MSDS-SDS Hazard Statement of Bismuth Subgallate:

Bismuth Subgallate SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet
24-Jun-21

1. Product Identification

Product Name & Other Names: Bismuth Subgallate, 2,7-Dihydroxy-1,3,2-benzodioxabismole-5-carboxylic acid, Bismuth(III) gallate basic hydrate, Dermatol.
CAS No.: 99-26-3 or 149-91-7
EINECS EC Number: 202-742-2
Molecular Weight: 394.09
Chemical Formula: C7H5BiO6
Relevant uses and uses advised against (if any): Laboratory and Industrial use only.
Supplier: As per letterhead.

2: Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
This substance is not classified as dangerous according to Directive 67/548/EEC.

Labeling according to GHS & Regulation (EC) No 1272/2008

GHS Label Elements
NONE

Signal Word: None

Precautionary statements:
P261: Avoid breathing dust/fume/gas/mist/vapors/spray.
P262: Do not get in eyes, on skin, or on clothing.
P281: Use personal protective equipment as required.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

3. Composition/Information on Ingredients

Product Name & Other Names: Bismuth Subgallate, 2,7-Dihydroxy-1,3,2-benzodioxabismole-5-carboxylic acid, Bismuth(III) gallate basic hydrate, Dermatol.
CAS No.: 99-26-3 or 149-91-7
EINECS EC Number: 202-742-2

4. First Aid Measures

Always seek medical advice after the first aid treatment.

Skin: Wash exposed area with soap and water.
Eyes: Wash eyes with plenty of water for at least 15 minutes, lifting lids occasionally. Seek Medical Aid.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Ingestion: If swallowed, induce vomiting immediately after giving two glasses of water. Never give anything by mouth to an unconscious person.

5. Fire Fighting Measures

Fire: It is not considered to be a fire hazard.
Explosion: Not considered to be an explosion hazard.
Fire Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical, or carbon dioxide. Use means suitable for extinguishing surrounding fire.
Extinguishing Media Not recommended: None specified.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.

6. Accidental Release Measures

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep-up and remove to an approved disposal container.

7. Handling and Storage

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like oxidizing agents. Containers of this material may be hazardous when empty since they retain product residues.

8. Exposure Controls/Personal Protection

Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume, or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit.
Exposure Limits: No specific OES assigned, however for dusts of any kind, ensure LTEL (8-hour TWA ref. period) level does not exceed 10 mg.m3 for total inhalable dust or 4 mg.m3 for respirable dust (or) as recommended in current edition of EH40. Consult local authorities for acceptable exposure limits.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. Physical and Chemical Properties

Appearance: It is fine, light yellow powder.
Odor: Odorless.
Odor threshold: Not available.
pH: Not available.
Relative density: 1.1
Melting point/freezing point: Not available.
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Insoluble in water.
Viscosity: Not available.
Molecular Weight: 394.09
Chemical Formula: C7H5BiO6

10. Stability and Reactivity

Stability: It is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: When heated to decomposition, emits bismuth oxide, fumes and liberates carbon dioxide.
Hazardous Polymerization: Will not occur.
Incompatibilities: Oxidizing agents.
Conditions to Avoid: Heat, incompatibles.

11. Toxicological Information

Toxicity to Animals: Not available.
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as possible or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Teratogenic Effects: Not available.
Mutagenic Effects: Not available.
Developmental Toxicity: Not available.
Reproductive Effects: No information available.

12. Ecological Information

Toxicity to fish: No information available.
Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container of and unused contents in accordance with federal, state, and local requirements.

14. Transport Information

Land Transport DOT USA, TDG Canada and ADR/RID Europe: Not dangerous goods.
Sea Transport IMO/IMDG: Not dangerous goods.
Air Transport ICAO/IATA: Not dangerous goods.

15. Regulatory Information

USA Regulations:
SARA 311/312 Hazards: No SARA Hazards. See section 2.
California Proposition 65: This product does not contain any Proposition 65 chemicals.

16. Other Information

DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources, and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules, or insurance requirements applicable. This SDS MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a professionally trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. This shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. In no case shall our company be liable to loss or damages by the product user.

Muby Chem P Ltd

Bismuth Subgallate Manufacturers, Suppliers, Exporters, Wholesellers:

King of Chemicals manufacturers

Muby Chem Private Limited
Plot No. 2900/46&47 + 2900/163to167, GIDC, Ankleshwar, Dist. Bharuch, India
India, USA, UAE
TEL: (Office) 91-22-23774610, 91-22-23723564

email: info@kingofchemicals.com

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Our products are for industrial and laboratory use only. The user must test the material before use. We are not dispensing chemists or druggist and do not offer over the counter type (OTC) products for medical use by individuals.

We and our associates manufacture pure chemicals surpassing Monograph Specifications of Analytical Reagent Standards, British & European Pharmacopoeia BP Ph Eur EP Standard, US Pharmacopoeia USP NF Standard, Indian Pharmacopoeia IP Standard, Japan Pharmacopoeia JP Standard, FCC Food Grade Standard.

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